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Journal of Porous Materials

, Volume 26, Issue 1, pp 261–269 | Cite as

Iron-doped mesoporous silica, Fe-MCM-41, as an active Lewis acid catalyst for acidolysis of benzyl chloride with fatty acid

  • Zhuxiu Zhang
  • Mengnan Hu
  • Qiumin Mei
  • Jihai TangEmail author
  • Zhaoyang Fei
  • Xian Chen
  • Qing Liu
  • Mifen CuiEmail author
  • Xu Qiao
Article
  • 111 Downloads

Abstract

Iron-doped mesoporous silica, Fe-MCM-41, with different concentrations of Lewis acidity have been prepared by the hydrothermal method. Physicochemical properties of all Fe-MCM-41 samples were obtained via HRTEM, PXRD and N2 sorption characterization. The surface acidities were tested by NH3-TPD. The catalytic activity of all Fe-MCM-41 materials were evaluated in the acidolysis reaction of benzyl chloride with various fatty acids. The corresponding benzaldehyde and acyl chloride product were synthesized in good conversion and high atom efficiency over the catalyst with the highest Fe content.

Keywords

Fe-MCM-41 Lewis acid catalyst Acidolysis Coproduction 

Notes

Acknowledgements

The author gratefully acknowledges the financial support from National Key R&D Program of China (2017YFB0307304), National Natural Science Foundation of China (21676141, 21606130), Natural Science Foundation of Jiangsu Province (BK20170989), Natural Science Foundation of Jiangsu Higher Education Institutions of China (17KJB530005), Six Major Talent Peak Project of Jiangsu Province (XCL-017) and Project “333” of Jiangsu Province (BRA2016418).

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Zhuxiu Zhang
    • 1
  • Mengnan Hu
    • 1
  • Qiumin Mei
    • 1
  • Jihai Tang
    • 1
    • 2
    Email author
  • Zhaoyang Fei
    • 1
  • Xian Chen
    • 1
  • Qing Liu
    • 1
  • Mifen Cui
    • 1
    Email author
  • Xu Qiao
    • 1
    • 2
  1. 1.State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical EngineeringNanjing Tech UniversityNanjingChina
  2. 2.Jiangsu National Synergetic Innovation Centre for Advanced Materials (SICAM)Nanjing Tech UniversityNanjingChina

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