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Journal of Porous Materials

, Volume 25, Issue 5, pp 1309–1316 | Cite as

Rapid and phase pure synthesis of microporous copper silicate (CuSH–1Na) with 12-ring channel system

  • Armandina M. L. Lopes
  • Zhi Lin
  • Stanislav Ferdov
Article
  • 185 Downloads

Abstract

Phase pure sample of the microporous copper silicate CuSH–1Na has been obtained by simplified hydrothermal method without using additives (H2O2 and Na2HPO4). Ion exchange of Na+ by Cs+, Ca2+ and Sr2+ ions showed that the structure can suffer partial replacement of the charge compensating cations. Ion exchange with Cs+ resulted in distinct dehydration while the ion exchange with Sr2+ increased the total amount of water. Water content in the Ca-exchanged sample is comparable to the as-synthesized sodium phase. Raman spectroscopy revealed that the divalent cations as Ca2+ and Sr2+ induce stronger local structural deformations than the monovalent Cs+. These structural changes have been also followed by the refined lattice distortions. Magnetic analyses showed that CuSH–1Na presents a very weak ferromagnetic interaction along the Cu2+ chains with a nearly vanishing Curie–Weiss temperature. This magnetic coupling is associated with super-super-exchange interactions through Cu–Na–O–Na–Cu paths. Antiferromagnetic coupling, attributed to inter-chains super-super-exchange interactions, competes with the ferromagnetic one and prevails at the lowest temperature.

Keywords

Microporous copper silicate CuSH–1Na Rapid synthesis Ion exchange Raman Thermal properties Magnetic properties 

Notes

Acknowledgements

This work was supported by the Portuguese Foundation for Science and Technology (IF/01516/2013 and IF/00686/2014).

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Authors and Affiliations

  1. 1.IFIMUP and IN - Institute of Nanoscience and NanotechnologyDepartamento de Física e Astronomia da Faculdade de Ciências da Universidade do PortoPortoPortugal
  2. 2.Department of Chemistry, CICECO - Aveiro Institute of MaterialsUniversity of AveiroAveiroPortugal
  3. 3.Department of PhysicsUniversity of MinhoGuimarãesPortugal

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