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Journal of Porous Materials

, Volume 25, Issue 4, pp 1091–1097 | Cite as

A novel pored supramolecular compound (C4H6N3)2·(P2Mo18O62)·(C4H7N3)2·(H2O)4: synthesis, crystal structure and photochromic property

  • Hanxi Xiao
  • Yilan Huang
  • Chunlin Teng
  • Qing Cai
  • Tiejun Cai
  • Qian Deng
Article
  • 74 Downloads

Abstract

A novel organic–inorganic supramolecular compound (C4H6N3)2·(P2Mo18O62)·(C4H7N3)2·(H2O)4 was synthesized through hydrothermal methods and characterized by IR spectroscopy, UV–Vis, Fluorescence spectra, TG-DTA, single-crystal X-ray diffraction. The results indicate that the compound exhibit a two-dimensional supramolecular network via hydrogen bond interactions. Crystal data: orthorhombic, Pnma space group, a = 25.4728 (17) Å, b = 20.3269 (8) Å, c = 15.6810 (7) Å, V = 8119.4 (7) Å3, Z = 4, R1 = 0.1285, wR2 = 0.2214. There is a pore structure between six [P2Mo18O62]6− along the b-axis. The accessible volume is 17.9% as estimated using the SOLV function of PLATON. The color of this compound is gradually turned from yellow into green in the ultraviolet irradiation with UV lamp (8W, 253 nm) for 2 h. It is indicated that the compound has photochromic property.

Keywords

Heteropolyoxoanion 2-Aminopyrimidine Porosity Crystal structure Photochromic property 

Notes

Acknowledgements

This work was supported by Scientific Research Project of Hunan Province Education Department of China (No. 14C0459).

Supplementary material

10934_2017_520_MOESM1_ESM.rar (60 kb)
Supplementary material 1 (RAR 59 KB)

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Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • Hanxi Xiao
    • 1
  • Yilan Huang
    • 1
    • 2
  • Chunlin Teng
    • 3
  • Qing Cai
    • 4
  • Tiejun Cai
    • 1
  • Qian Deng
    • 1
  1. 1.Key Laboratory of Theoretical Organic Chemistry and Functional Molecules of Ministry of Education, School of Chemistry and Chemical EngineeringHunan University of Science and TechnologyXiangtanChina
  2. 2.Analytic Testing CenterShenzhen Hangsen Star Technology Co., Ltd.ShenzhenChina
  3. 3.Department of ChemistrySun Yat-Sen UniversityGuangzhouChina
  4. 4.Lachman Institute for Pharmaceutical AnalysisLong Island University-Brooklyn CampusBrooklynUSA

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