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Journal of Porous Materials

, Volume 24, Issue 4, pp 1095–1103 | Cite as

Catalytic performance study of nano-cobalt: a catalyst for complement to the Heck coupling reaction

  • K. S. Jithendra Kumara
  • G. Krishnamurthy
  • B. E. Kumara Swamy
  • N. Sunil Kumar
  • Mohan Kumar
Article

Abstract

Easy and convenient synthesis of crystalline cobalt-nanoparticles by a seed mediated growth method with cetyltrimethylammonium bromide used as surfactant, KI as an additive and ascorbic acid as reductant; this synthesized Co-nanoparticle are characterized by XRD and TEM analysis, and is used as a coupling catalyst for alkenes with aryl halides in the presence of a base. The yield of the catalyzed product and the method has many advantages such as affordable and ligand-free condition. Hence overall reaction is augmented to the Heck coupling reaction.

Keywords

Cobalt-nanoparticles (Co-NPs) Seed-mediated method Heck reaction Low-cost catalyst Ligand-free condition 

Notes

Funding

The funding was provided by University Grants Commission (Grant No. UGC:MRP(S)-0098/12-13/KAKU023/UGC-SWRO/dated:01-10-2013).

Supplementary material

10934_2016_350_MOESM1_ESM.docx (5.7 mb)
Supplementary material (DOCX 5876 KB)

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • K. S. Jithendra Kumara
    • 1
  • G. Krishnamurthy
    • 1
  • B. E. Kumara Swamy
    • 2
  • N. Sunil Kumar
    • 1
  • Mohan Kumar
    • 2
  1. 1.Department of ChemistrySahyadri Science CollegeShivamoggaIndia
  2. 2.Department of Industrial ChemistryKuvempu UniversityShivamoggaIndia

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