Journal of Porous Materials

, Volume 22, Issue 4, pp 843–850 | Cite as

An investigation into the crystallization of low-silica X zeolite

Article

Abstract

The crystallization of low-silica X (LSX) zeolite with FAU topology was examined under hydrothermal synthesis conditions. PXRD was employed to follow the evolution of the long-range ordering of the gel. Raman spectra provided information on various ring and cage species existing in the gel. 27Al and 29Si solid-state NMR spectroscopy was utilized to monitor the change in local environment of tetrahedral sites. The results indicate that an amorphous aluminosilicate phase was formed immediately upon mixing different reactive species. Hydrothermal treatment led to the formation of sodalite-cage like species and the species with larger cavities, joint four-member rings (4Rs) and branched 4Rs, which are the structural building units of the FAU framework. These units were assembled into the crystalline structure of LSX zeolite. 23Na and 39K solid-state NMR results show that the transformation process was accompanied by the changes of the local structure of hydrated Na+ and K+ ions. The two types of cations may work synergistically to template the crystallization of LSX zeolite.

Keywords

Zeolites Faujasite Crystallization Hydrothermal synthesis Solid-state NMR Raman spectroscopy 

Notes

Acknowledgments

Y. H. thanks the Natural Science and Engineering Research Council of Canada for a Discovery grant. Access to the 900 MHz NMR spectrometer was provided by the Canadian National Ultrahigh Field NMR Facility for Solids (http://nmr900.ca). We thank Dr. V. Terskikh for acquiring 39K NMR spectra and Mr. P. He for 39K spectral simulation. We also thank Prof. Yang Song for the access of a Raman spectrometer. This work was funded by the Natural Science and Engineering Research Council of Canada (2012).

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.Department of ChemistryThe University of Western OntarioLondonCanada

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