Journal of Porous Materials

, Volume 19, Issue 4, pp 465–472 | Cite as

Infrared investigations of arenesulfonic modified mesoporous materials by the use of complementary probes

Article

Abstract

Arenesulfonic mesoporous materials [SBA(R), 0.05 ≤ R (incorporation ratio) ≤0.15] have been prepared by the co-condensation of tetraethoxysilane (TEOS) and 2-(4-chlorosulfonylphenyl) ethyltrimethoxysilane (CSPTMS) in acidic solutions of Pluronic P123. The extent of the surface functionalisation and the nature of the interactions between sulfonic groups and the surface in SBA(0.05) and SBA(0.15) samples were investigated by FT-IR spectroscopy using two probes of different basic strengths. It was shown that carbon monoxide (CO, at 77 K) can be used as a good probe to study the surface functionalisation through the νC=O vibration at 2,158 cm−1 corresponding to its interaction with free silanol groups. Ammonia (NH3, at 423 K) is able to disturb the strong interactions of Si–OH–H3OS by forming the δNH–NH4+ which allowed to emphasise that SO3H groups of the less functionalised material SBA(0.05) are less acidic since the number of the acid groups is less important than in SBA(0.15).

Keywords

Carbon monoxide Ammonia Arenesulfonic Acidity FT-IR 

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Pétra Salamé
    • 1
  • Olivier Marie
    • 2
  • Wei Zhao
    • 3
  • Virginie Semmer-Herlédan
    • 1
  • Franck Launay
    • 1
  • Antoine Gédéon
    • 1
  1. 1.Laboratoire des Systèmes Interfaciaux à l’Echelle NanométriqueCNRS UMR 7142, Université Pierre et Marie CurieParisFrance
  2. 2.Laboratoire Catalyse et SpectrochimieCNRS-UMR 6506, ENSICAENCaen CedexFrance
  3. 3.Institute of Process EngineeringChinese Academy of SciencesBeijingPeople’s Republic of China

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