Journal of Porous Materials

, Volume 19, Issue 2, pp 153–160 | Cite as

Formation of a Ti-siliceous trimodal material with macroholes, mesopores and zeolitic features via a one-pot templating synthesis

  • Jarian Vernimmen
  • Vera Meynen
  • Myrjam Mertens
  • Oleg I. Lebedev
  • Gustaaf Van Tendeloo
  • Pegie Cool
Article
First Online:

Abstract

Based on a facile one-pot templating synthesis, using a TS-1 zeolite recipe whereby part of the zeolite structure directing agent is replaced by a mesopore templating agent, a trimodal material is formed. The resulting meso-TSM material combines mesoporosity (Ti-MCM-41) with zeolitic features (TS-1) and a unique sheet-like morphology with uniform macroporous voids (macroholes). Moreover, the macrohole formation, mesoporosity and zeolitic properties of the meso-TSM material can be controlled in a straightforward way by adjusting the length of the hydrothermal treatment. This newly developed material may imply great potential for catalytic redox applications and diffusion limitated processes because of its highly tunable character in all three dimensions (micro-, meso- and macroporous scale).

Keywords

Combined zeolitic/mesoporous materials TS-1 Ti-MCM-41 One-pot synthesis Worm-like material Macroholes 
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Notes

Acknowledgments

J. Vernimmen thanks the Fund for Scientific Research-Flanders (FWO-Vlaanderen) for financial support. The Concerted Research Project (CRP, GOA-project) sponsored by the Special Fund for Research at the University of Antwerp is acknowledged.

Supplementary material

10934_2011_9470_MOESM1_ESM.doc (1.9 mb)
Supplementary material 1 (DOC 1991 kb)

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Jarian Vernimmen
    • 1
  • Vera Meynen
    • 1
  • Myrjam Mertens
    • 2
  • Oleg I. Lebedev
    • 3
    • 4
  • Gustaaf Van Tendeloo
    • 4
  • Pegie Cool
    • 1
  1. 1.Department of Chemistry, Laboratory of Adsorption and CatalysisUniversity of Antwerp, CDEWilrijkBelgium
  2. 2.Flemish Institute for Technological Research (VITO N.V.)MolBelgium
  3. 3.CRISMAT, UMR 6508, CNRS-ENSICAENCaenFrance
  4. 4.EMAT, Department of PhysicsUniversity of Antwerp, CGBAntwerpBelgium

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