Journal of Porous Materials

, Volume 18, Issue 5, pp 639–650 | Cite as

Synthesis of layered MCM-22(P) in the presence of hexamethonium cations and its transformation into EUO- and MWW-type zeolites

  • Simone Goergen
  • Elie Fayad
  • Sébastien Laforge
  • Patrick Magnoux
  • Loïc Rouleau
  • Joël Patarin
Article
First Online:

Abstract

Layered MCM-22(P) was synthesized in the presence of hexamethonium (HM) cations. Compared to zeolite EU-1 (EUO-type structure), which crystallizes in similar conditions, its formation is favored at high HM concentrations (HM/SiO2 ≥ 0.3) and in the absence of Na2O. HM-containing MCM-22(P) was used as starting material for zeolite formation. Upon hydrothermal treatment, HM-MCM-22(P) transforms into zeolite EU-1 and upon calcination into a MWW-type zeolite. Transformation mechanisms were studied by standard characterization techniques such as XRD, SEM and TEM. Catalytic properties of the MWW-type zeolite obtained from this precursor were evaluated in a m-xylene isomerization reaction. Compared to zeolite MCM-22 prepared with hexamethyleneimine, a higher catalytic activity and an increased isomerization selectivity were observed and discussed.

Keywords

Layered aluminosilicate MCM-22(P) EUO-type zeolite MWW-type zeolite Zeolite synthesis m-Xylene isomerization 
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Notes

Acknowledgments

The authors would like to give special thanks to Bernadette Rebours, Fanny Tihay, Emmanuelle Trela-Baudot (IFP-Lyon) and Mohammed Ali Saada, Séverinne Rigolet (MPC-IS2 M-Mulhouse) for their contribution to the characterization of the samples.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Simone Goergen
    • 1
    • 2
    • 4
  • Elie Fayad
    • 1
  • Sébastien Laforge
    • 3
  • Patrick Magnoux
    • 3
  • Loïc Rouleau
    • 1
  • Joël Patarin
    • 2
  1. 1.IFP Energies nouvellesDirection Catalyse et SéparationSolaizeFrance
  2. 2.Equipe Matériaux à Porosité Contrôlée (MPC)Institut de Science des Matériaux de Mulhouse (IS2M)MulhouseFrance
  3. 3.Equipe “Catalyse sur Zéolithes et Solides Apparentés”Laboratoire de Catalyse en Chimie Organique (LACCO)PoitiersFrance
  4. 4.Department of Chemical and Biological EngineeringTufts UniversityMedfordUSA

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