Journal of Porous Materials

, Volume 15, Issue 2, pp 127–132 | Cite as

Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41

  • Jinbao Gao
  • Liang Lu
  • Wenjuan Zhou
  • Guohua Gao
  • Mingyuan He
Article
First Online:

Abstract

Vanadyl Schiff base complexes covalently attached on the surface of MCM-41 have been synthesized by anchoring Schiff base and subsequent reaction with VO(acac)2. XRD, nitrogen adsorption and desorption, UV-visible spectroscopy and FT-IR show that vanadyl Schiff base complexes were successfully anchored on the surface of MCM-41 and the mesopore ordering decreased after the anchoring. The so-prepared heterogeneous catalysts have showed high activity for sulfide oxidation.

Keywords

Heterogeneous catalysis Vanadyl Schiff base complexes Mesoporous Sulfide oxidation 
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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Jinbao Gao
    • 1
  • Liang Lu
    • 1
  • Wenjuan Zhou
    • 1
  • Guohua Gao
    • 1
  • Mingyuan He
    • 1
  1. 1.Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical ProcessEast China Normal UniversityShanghaiChina

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