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Journal of Polymers and the Environment

, Volume 20, Issue 4, pp 1084–1094 | Cite as

Layer-by-Layer Deposition of Antibacterial Polyelectrolytes on Cotton Fibres

  • Ana P. Gomes
  • João F. Mano
  • João A. Queiroz
  • Isabel C. Gouveia
Original Paper

Abstract

The introduction of molecules with biological properties on textile materials is essential for a number of biotechnological applications. With the purpose of testing new processes applied to textiles, in this study, we present the first results on the feasibility of using the Layer-by-Layer (LbL) deposition process in natural fibers such as cotton, with natural polyelectrolytes like chitosan (CH) and alginic acid sodium salt (ALG), the durability of CH/ALG multilayer on cotton were evaluated. The increase of negative charges to the substrate cotton was made with NaBr and TEMPO, to ensure the success of the process of LbL. Three characterization methods to assess electrostatic LbL deposition were performed: the contact angle between a liquid (water) and the sample surface, in order to characterize the wettability of the samples with the different layers of CH and ALG; dyeing of the CH/ALG assembled cotton fabric with cationic methylene blue that shows regular changes in terms of color depth (K/S value), which indicate that the surface were alternately deposited with CH and ALG layers and, finally, the analysis by infrared spectroscopy using Fourier Transform with Attenuated Total Reflection (ATR-FTIR), to assess the changes in the interaction between CH and ALG deposited on cotton samples.

Keywords

Layer-by-layer Contact angle ATR-FTIR Chitosan Alginate 

Notes

Acknowledgments

The authors wish to acknowledge the Fundação para a Ciência e Tecnologia and Compete for the financial support of the project: PTDC/EBB-BIO/113671/2009 Skin2Tex.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Ana P. Gomes
    • 1
  • João F. Mano
    • 2
    • 3
  • João A. Queiroz
    • 4
  • Isabel C. Gouveia
    • 5
  1. 1.Optical Centre, University of Beira InteriorCovilhãPortugal
  2. 2.3B’s Research Group, Biomaterials, Biodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative Medicine, University of MinhoTaipasPortugal
  3. 3.ICVS/3B’s, PT Government Associate LaboratoryBragaPortugal
  4. 4.Health Sciences Research Centre, University of Beira InteriorCovilhãPortugal
  5. 5.R&D Unit of Textile and Paper Materials, Faculty of EngineeringUniversity of Beira InteriorCovilhãPortugal

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