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Journal of Polymers and the Environment

, Volume 12, Issue 4, pp 219–229 | Cite as

Influences of Magnesium tri-Silicate on the Physical, Mechanical, and Degradable Properties of Ultraviolet (UV) Radiation Cured Plain Board Surface

  • Mubarak A. KhanEmail author
  • M. Mizanur Rahman
  • M. Ahsan Habib
  • A. I. Mustafa
Article
  • 52 Downloads

Abstract

A series of formulations were prepared with different percentages of oligomer, epoxy diacrylate (EA-1020 ), monomer, 1,6 Hexane diol diacrylate,(HDDA) and different percentages of filler (Magnesium tri-silicate, Mg2Si3O8). Irgacure 369 [2-Benzyl-2-dimethyl-amine-1 (4-morpholinophenyl) butanone-1] was used in the formulations as photoinitiator. Ultraviolet (UV) cured thin polymer films were prepared from these formulating solutions on clean glass plates. Pendulum hardness (PH), gel content and macro scratch hardness (MSH) of the UV cured films were studied. One percent Mg2Si3O8 containing formulation showed the premium properties. The substrates (plain board) were coated by these formulating solutions and cured under the same UV lamp at different intensities of radiation. Various properties of the coated surface such as PH, gloss, adhesion, abrasion and MSH were investigated. The base coat containing 1% Mg2Si3O8 and top coat containing 48% HDDA produced the best performance among all the formulations inspected. The degradable properties in different weathering conditions on PH, gloss, adhesion, abrasion and MSH were measured. The surface cured with the optimized formulation (E) again yielded the minimum loss of the properties.

Keywords

Plain board UV curing degradable properties magnesium tri-silicate 

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References

  1. Karmaker, A. C., Hinrichsen, G. 1991Polym. Plast. Technol. Engg.30609Google Scholar
  2. Maldas, D., Kokta, B. V. 1990Polym. Plast. Technol. Engg.29119Google Scholar
  3. Raj, R. G., Kokta, B. V., Grouuleau, G., Daneault, C. 1990Polym. Plast. Technol. Engg.29339Google Scholar
  4. Khabiruddin, M., Khan, M. A., Idriss Ali, K. M. 1997Polym. Degrad. Stab.551Google Scholar
  5. Mizanur Rahman, M., Khn, M. A., Khabiruddin, M., Idriss Ali, K. M., Mustafa, A. I. 2001J. Appl. Polym. Sci.811858Google Scholar
  6. M. A. Khan, M. Mizanur Rahman, M. Z. R. Bhuiyan, and M. U. Ahmad (2002) J. Appl. Polym. Sci. 86 (in press).Google Scholar
  7. Idriss Ali, K. M., Khan, M. A., Niazul Islam, M. 1997J. Appl. Polym. Sci.6611Google Scholar
  8. Khan, M. A., Khabiruddin, M., Nurul Islam, M., Idriss Ali, K. M. 1995J. Appl. Polym. Sci.5831Google Scholar
  9. Mizanur Rahman, M., Khan, M. A., Mustafa, A. I. 2002J. Appl. Polym. Sci.862385Google Scholar
  10. Idriss Ali, K. M., Khan, M. A., Rahman, Mokhlesur, Gani, Mahmuda 1997J. Appl. Polym. Sci.661997Google Scholar
  11. Mizanur Rahman, M., Khan, M. A., Mustafa, A. I. 2002Polym Plast. Technol. Engg.411Google Scholar
  12. Khan, M. A., Rahman, M. M., Idriss Ali, K. M. 2001Polym. Plast. Technol. Engg.39105Google Scholar
  13. Green, G. E., Stark, B. P., Zahir, S. A. 1982J. Macromol. Sci. Rev. Macromol. Chem.C 21187Google Scholar
  14. Anseth, K. S., Wang, C. K., Bowman, C. N. 1994Polymer353243Google Scholar
  15. Decker, C., Moussa, K. 1989Macromolecules224455Google Scholar
  16. Basher, A. S., Khan, M. A., Idriss Ali, K. M. 1996Radiat. Phys. Chem.44350Google Scholar
  17. Khan, M. A., Nurul Islam, M., Hossain, Altaf 1996Radiat. Phys. Chem.48339Google Scholar
  18. Banik, I., Bhowmik, A. K. 1998J. Appl. Polym. Sci.692079Google Scholar
  19. Idriss Ali, K. M., Khan, M. A., Islam, M. N. 1996Polym Plast. Technol. Engg.35299Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • Mubarak A. Khan
    • 1
    Email author
  • M. Mizanur Rahman
    • 2
  • M. Ahsan Habib
    • 3
  • A. I. Mustafa
    • 3
  1. 1.Radiation and Polymer Chemistry Laboratory, Institute of Nuclear Science and TechnologyBangladesh Atomic energy CommissionDhakaBangladesh
  2. 2.Department of ChemistryBangladesh Institute of Technology (BIT)Dhaka, GazipurBangladesh
  3. 3.Department of Applied Chemistry and Chemical TechnologyUniversity of DhakaDhakaBangladesh

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