(BETS)2[RuX5NO] (X = Cl, Br): An Explanation of Different Conductive Properties Through Structural and Spectroscopic Studies
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(BETS)2[RuX5NO] (X = Cl, Br) exhibit an identical 2:1 stoichiometry. However, while the chlorine derivative shows an insulating behavior, the bromine behaves as a semiconductor with very small activation energy (0.03 eV). The different electrical behaviors are analyzed through the use of a detailed study of structural data and analysis of Raman spectra
PACS Numbers72.80.Le 61.10.Nz 78.30.Jw 33.20Fb
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