Synthesis of a Conductive Glassy System Based on Inorganic Oxides and Carbon Materials and Their Possible Electroanalytical Application

  • Gastón Darío PieriniEmail author
  • Pablo Emanuel di Pratula
  • Ana Laura Ochoa
  • María Eugenia Centurión
  • Marisa Alejandra Frechero
  • María Susana Di NezioEmail author


New materials based on V2O5, TeO2 and a combination of graphite, graphene oxide and multiwalled carbon nanotubes were developed and tested as potential electrochemical sensors. A mixture design with three components in combination with multi-response assays based on the desirability function was used as multivariate optimization for the system composition. The optimal sensor contains graphene oxide and multiwalled carbon in approximately equal amounts. The new sensors characterizations were performed with X-ray diffraction, differential scanning calorimetry, impedance spectroscopy and cyclic voltammetry. The main advantage of this electrodes are does not requires surface activation and exhibited a potential electroanalytical performance with different targeted analytes such as ascorbic acid, aspartame and lead.


Conductive glassy system Graphene oxid Multiwalled carbon nanotubes Electrochemical sensor 



G.D.P., P.E.dP. and A.L.O. are fellowships and M.A.F is Research Fellow of the CONICET, Argentina. The authors acknowledge the financial support from SGCyT—Universidad Nacional del Sur, Argentina (PGI 24/Q077) and INQUISUR-CONICET.

Supplementary material

10904_2019_1434_MOESM1_ESM.docx (130 kb)
Supplementary file1 (DOCX 130 kb)


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2020

Authors and Affiliations

  • Gastón Darío Pierini
    • 1
    Email author
  • Pablo Emanuel di Pratula
    • 1
  • Ana Laura Ochoa
    • 2
  • María Eugenia Centurión
    • 1
  • Marisa Alejandra Frechero
    • 1
  • María Susana Di Nezio
    • 1
    Email author
  1. 1.Departamento de QuímicaINQUISUR (UNS-CONICET), Universidad Nacional del SurBuenos AiresArgentina
  2. 2.Departamento de Química, Facultad de Ciencias ExactasFísico-Químicas y Naturales, Universidad Nacional de Río CuartoRío CuartoArgentina

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