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Photocatalytic Degradation of 2,4-Dichlorophenoxyacetic Acid in Aqueous Solution Using Mn-doped ZnO/Graphene Nanocomposite Under LED Radiation

  • Roya Ebrahimi
  • Mahnaz Mohammadi
  • Afshin MalekiEmail author
  • Ali Jafari
  • Behzad Shahmoradi
  • Reza Rezaee
  • Mahdi Safari
  • Hiua Daraei
  • Omid Giahi
  • Kaan YetilmezsoyEmail author
  • Shivaraju Harikaranahalli Puttaiah
Article
  • 24 Downloads

Abstract

Chemical pesticides and herbicides are one of the most important pollutants in urban, agricultural and industrial wastewaters. Improper discharge of these compounds into water bodies’ cause harmful effects on both environment and human health. In this study, photocatalytic degradation of 2,4-Dichlorophenoxyacetic acid (usually called 2,4-D) was investigated using Mn-doped zinc oxide/graphene nanocomposite under light emitting diodes (LED) radiation. FTIR, AFM, DLS, Zeta potential, XRD, and SEM techniques were used to determine the characteristics of the nanocomposite. The effects of process-related parameters, such as the amount of nanocomposite, initial pH, 2,4-D concentrations, and contact time, on the photocatalytic degradation of the 2,4-D were studied. The results showed that the efficiency of photocatalytic degradation of 2,4-D decreased with an increase in the initial concentration of 2,4-D, while photocatalytic degradation efficiency increased by increasing the initial pH and the nano-catalyst content. The results showed that 66.2% of 2,4-D could be photocatalytically degraded using Mn-doped zinc oxide/graphene nanocomposite under LED radiation at optimal conditions (pH 5, initial Zn concentration of 10 mg L−1, nano-composite concentration of 2 g L−1, contact time of 120 min). Findings of this experimental study concluded that photocatalysis using Mn-doped zinc oxide/graphene nanocomposite under LED radiation could efficiently remove 2,4-D herbicide from aqueous media.

Keywords

LED radiation ZnO Nanocomposite 2,4-Dichlorophenoxyacetic acid Graphene 

Notes

Acknowledgements

The authors offer their special thanks to the sponsors of the project.

Funding

This manuscript is extracted from the project approved by the Environmental Health Research Center and funded by the Kurdistan University of Medical Sciences (Grant No. IR.MUK.REC.1395/236).

Compliance with Ethical Standards

Conflict of interest

The authors declare that there are no conflicts of interest including any financial, personal, or other relationships with other people or organizations.

Research Involving Human and Animal Participants

This article does not contain any studies with human participants or animals performed by any of the authors.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Environmental Health Research Center, Research Institute for Health Development, Kurdistan University of Medical SciencesSanandajIran
  2. 2.School of HealthLorestan University of Medical SciencesKhorramabadIran
  3. 3.Department of Environmental Engineering, Faculty of Civil EngineeringYildiz Technical UniversityIstanbulTurkey
  4. 4.Department of Water and Health, Faculty of Life SciencesJagadguru Sri Shivarathreeshwara UniversityMysuruIndia

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