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NiMo/C Used as Magnetic Support for SILP Catalysts

  • Evelisy C. O. Nassor
  • Raquel V. Mambrini
  • Eduardo N. dos Santos
  • Flávia C. C. Moura
  • Maria Helena Araujo
Article
  • 2 Downloads

Abstract

In this work, supported ionic liquid (IL) phases catalysts were prepared based on Pd dispersed in IL phases supported on magnetic particles of nickel/molybdenum covered with carbon (NiMo/C). The magnetic support was prepared via CVD method at 800 °C. XRD analysis showed the phases of metallic nickel and molybdenum carbide. The presence of carbon in these materials was confirmed by TEM/EDS and thermogravimetric analysis (TG) analysis. Pd particles were dispersed in 1 and 2.5 wt% of the IL 1-butyl-3-methylimidazolium tetrafluoroborate (BMIm·BF4), which were immobilized on the support surface via impregnation method. TG analysis shows a weight loss between 300 and 420 °C attributed to the BMIm·BF4, confirming the existence of IL on the support surface. The prepared materials were investigated in hydrogenations reactions of 1,5-cyclooctadiene and nitrobenzene, and the influence of IL on the activity and selectivity of these catalysts were observed. These materials have great potential for catalysis applications, because they bring together the advantages of the IL in the catalyst surface and the facility of magnetic materials separation.

Keywords

Ionic liquid SILP catalysts Magnetic supports Hydrogenation 

Notes

Acknowledgements

The authors acknowledge the financial support provided from FAPEMIG, PRPq/UFMG, PETROBRÁS, CNPq and CAPES.

Compliance with Ethical Standards

Conflict of interest

The authors declared that there are no known conflicts of interest associated with this publication and there has been no significant financial support for this work that could have influenced its outcome.

Supplementary material

10904_2018_911_MOESM1_ESM.docx (98 kb)
Supplementary material 1 (DOCX 98 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Evelisy C. O. Nassor
    • 1
  • Raquel V. Mambrini
    • 2
  • Eduardo N. dos Santos
    • 3
  • Flávia C. C. Moura
    • 3
  • Maria Helena Araujo
    • 3
  1. 1.Instituto Federal de Minas GeraisPiumhiBrazil
  2. 2.Departamento de QuímicaCentro Federal de Educação Tecnológica de Minas GeraisBelo HorizonteBrazil
  3. 3.Departamento de Química, Instituto de Ciências ExatasUniversidade Federal de Minas GeraisBelo HorizonteBrazil

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