In situ Synthesis, Crystal Structure and Photoluminescence of a Novel Coordination Polymer with (4,6,6)-Connected sqc111 Topology

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Abstract

Employing the mixed ligands to react with Cd(NO3)2·4H2O afforded a new 3D coordination polymer [Cd3(BPTC)(bmp)2(ox)(H2O)4] (1) (H4BPTC = biphenyl-3,3′,4,4′-tetracarboxylic acid, bmp = 3,6-bis(imidazol-1-yl)pyridazine, H2ox = oxalic acid), in which ox2− was from the in situ oxidation of ethanol. Compound 1 bears a novel trinodal (4,6,6)-connected net structure, and it is the first replica of the theoretically predicted sqc111 topology net. Moreover, the thermal and photoluminescent properties for 1 were also investigated.

Keywords

Coordination polymer Topology In situ ligand Photoluminescence Oxalate 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundations of China (No. 21663016), the Natural Science Foundations of Jiangxi Province (No. 2011ZBAB203013 and 20122BAB203010), and the Foundation of Educational Department of Jiangxi Province (No. GJJ12103).

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

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Supplementary material 1 (DOC 590 KB)
10904_2018_849_MOESM2_ESM.txt (22 kb)
Supplementary material 2 (TXT 21 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Institute of Applied Chemistry, College of ChemistryNanchang UniversityNanchangPeople’s Republic of China

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