Synthesis and Luminescence Properties of Immobilized Europium β-CD Complexes on Silica

  • Wen Jun Zhang
  • Yi Chen
  • Shao Pei Zhang
  • Shao Kang Tang
  • Xue Qing Chen
  • Guang Yu Cui
Article
  • 21 Downloads

Abstract

Functionalized silica gel organic–inorganic hybrid materials based on covalently grafted lanthanide coordinations onto organosilicone have been the subject of intense study due to their superior physicochemical properties. However, it cannot be assumed that all the primary guest molecules can be directly covalent-grafted onto the host that prevents H2O molecules from coordinating with the central ion; the introduction of a medium could be useful in this regard. In the present work, a medium β-cyclodextrin (β-CD) was employed, and by sol–gel and molecular assembly processes, immobilization of a europium–β-CD inclusion on silica and the preparation of a novel fluorescent polymeric hybrid material β-CD–TESPIC–TTA–Eu were achieved. This research shows that β-CD can prevent the H2O molecules from coordinating with the central ion Eu3+ (inclusion). The novel hybrid material has an amorphous and homogeneous network surface and exhibits excellent film-forming properties, bright-red light emission that is dominated by the 5D0 → 7F2 transition of Eu3+, and a lifetime of 0.44 ms.

Keywords

Molecular assembly Sol–gel preparation Polymeric europium complexes Optical materials 

Notes

Acknowledgements

The project was supported by Hebei Education Foundation (ZD2017214).

Supplementary material

10904_2018_787_MOESM1_ESM.doc (604 kb)
Supplementary material 1 (DOC 603 KB)

References

  1. 1.
    A.C. Franville, D. Zambon, R. Mahiou, S. Chou, Y. Troin, J.C. Cousseins, J. Alloys Compd. 275–277(98), 831–834 (1998)CrossRefGoogle Scholar
  2. 2.
    Y.-F. Shao, B. Yan, Z.-Y. Jiang, RSC Adv. 2(24), 9192 (2012).  https://doi.org/10.1039/c2ra21605a CrossRefGoogle Scholar
  3. 3.
    J.-N. Hao, B. Yan, New J. Chem. 38(8), 3540 (2014).  https://doi.org/10.1039/c4nj00466c CrossRefGoogle Scholar
  4. 4.
    Y. Li, X. Ge, X. Pang, X. Yu, X. Zhen, L. Geng, Y. Wang, Mater. Lett. 152, 170–172 (2015).  https://doi.org/10.1016/j.matlet.2015.03.127 CrossRefGoogle Scholar
  5. 5.
    Q. Xu, Z. Li, M. Chen, H. Li, CrystEngComm 18(1), 177–182 (2016).  https://doi.org/10.1039/c5ce01664a CrossRefGoogle Scholar
  6. 6.
    X. Guo, H. Guo, L. Fu, H. Zhang, L.D. Carlos, R. Deng, J. Yu, J. Photochem. Photobiol. A 200(2–3), 318–324 (2008).  https://doi.org/10.1016/j.jphotochem.2008.08.016 CrossRefGoogle Scholar
  7. 7.
    X.F. Qiao, B. Yan, Inorg. Chem. 48(11), 4714–4723 (2009).  https://doi.org/10.1021/ic8017776 CrossRefGoogle Scholar
  8. 8.
    X. Chen, P. Zhang, T. Wang, H. Li, Chemistry 20(9), 2551–2556 (2014).  https://doi.org/10.1002/chem.201303957 CrossRefGoogle Scholar
  9. 9.
    X. Sun, S. Sui, C. Ference, Y. Zhang, S. Sun, N. Zhou, W. Zhu, K. Zhou, J. Agric. Food Chem. 62(35), 8914–8918 (2014).  https://doi.org/10.1021/jf5027873 CrossRefGoogle Scholar
  10. 10.
    P.d..P. Menezes, M.R. Serafini, Y.M.B.G. de Carvalho, D.V. Soares Santana, B.S. Lima, L.J. Quintans-Júnior, R.N. Marreto, T.M. de Aquino, A.R. Sabino, L. Scotti, M.T. Scotti, S. Grangeiro-Júnior, A.A. de Souza Araújo, J. Mol. Struct. 1125, 323–330 (2016).  https://doi.org/10.1016/j.molstruc.2016.06.062 CrossRefGoogle Scholar
  11. 11.
    S. Hu, Y. Xu, D. Jiang, D. Wu, Y. Sun, F. Deng, Thin Solid Films 518(1), 348–354 (2009).  https://doi.org/10.1016/j.tsf.2009.06.024 CrossRefGoogle Scholar
  12. 12.
    S. Hu, D. Yang, Y. Xu, D. Wu, Y. Sun, Mater. Chem. Phys. 114(2–3), 868–873 (2009).  https://doi.org/10.1016/j.matchemphys.2008.10.071 CrossRefGoogle Scholar
  13. 13.
    C. Sun, C. Li, R. Qu, Y. Zhang, Z. Bingdong, Y. Kuang, Chem. Eng. J. 240, 369–378 (2014).  https://doi.org/10.1016/j.cej.2013.11.092 CrossRefGoogle Scholar
  14. 14.
    S.P. Zhang, H.O. Song, Chem. J. Chin. Univ. 33(6), 1214–1219 (2012)Google Scholar
  15. 15.
    Y. Yang, F. Gao, X. Cai, X. Yuan, S. He, F. Gao, H. Guo, Q. Wang, Biosens. Bioelectron. 74, 447–453 (2015).  https://doi.org/10.1016/j.bios.2015.06.018 CrossRefGoogle Scholar
  16. 16.
    Y.F. Shao, B. Yan, Z.Y. Jiang, RSC Adv. 2(24), 9192–9200 (2012)CrossRefGoogle Scholar
  17. 17.
    Y. Wang, C.W. Jin, S.M. He, N. Ren, J.J. Zhang, J. Mol. Struct. 1125, 383–390 (2016)CrossRefGoogle Scholar
  18. 18.
    Y. Li, B. Yan, Y. Li, J. Solid State Chem. 183(4), 871–877 (2010).  https://doi.org/10.1016/j.jssc.2010.02.006 CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Wen Jun Zhang
    • 1
  • Yi Chen
    • 1
  • Shao Pei Zhang
    • 1
  • Shao Kang Tang
    • 1
  • Xue Qing Chen
    • 1
  • Guang Yu Cui
    • 1
  1. 1.School of Chemical EngineeringHebei University of TechnologyTianjinChina

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