Syntheses and Properties of Two New Multi-functional Cobalt(II) Complexes Derived from Two Different Semi-rigid Bis(pyridyl)–Bis(amide) Ligands

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Abstract

Two new cobalt(II) complexes with the formulas of [Co(3-ebpba)(Hcppa)]n (1) and [Co(3-bpcd)(Hcppa)]n (2) have been obtained under the solvothermal conditions by reacting of two semi-rigid bis(pyridyl)–bis(amide) ligands with different spacers [3-ebpba = (E)-4,4′-(ethene-1,2-diyl)bis(N-pyridin-3-yl)benzamide, 3-bpcd = N,N′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide] and the aromatic tricarboxylic acid [H3cppa = 5-(4-carboxyl-phenoxy)-isophthalic acid]. Complex 1 represents a 2D polymeric layer constructed by the 1D [Co(Hcppa)]n ‘chinese knot’-shaped chains and µ2-bridging 3-ebpba ligands. Complex 2 is a 1D ribbon chain based on the 1D [Co(Hcppa)]n ‘comb’-liked chains and the bidentate 3-bpcd ligands. Finally, the adjacent 2D layers or 1D chains are extended to 3D supramolecular networks via hydrogen-bonding interactions for the title complexes. In addition, the electrochemical behaviors, fluorescent properties and the photocatalytic activities of two cobalt(II) complexes towards the degradation of organic dyes have been studied.

Keywords

Cobalt(II) complex Bis(pyridyl)–bis(amide) ligand Tricarboxylate Fluorescent properties Photocatalytic activity 

Notes

Acknowledgements

The supports of the National Natural Science Foundation of China (No. 21501013, 21401010) and Program for Distinguished Professor of Liaoning Province (No. 2015399) are gratefully acknowledged.

Supplementary material

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Supplementary material 2 (PDF 399 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of ChemistryBohai UniversityJinzhouPeople’s Republic of China

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