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1,3-Dithiolane and 1,3-Ferrocenyl-dithiolane as Assembling Ligands for the Construction of Cu(I) Clusters and Coordination Polymers

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Abstract

The parent compound 1,3-dithiolane L1 reacts with CuI providing the 2D coordination polymer (CP) [{Cu(μ2-I)2Cu}(μ2-L1)2] n (CP1). The Cu⋯Cu distance within the Cu(μ2-I)2Cu rhomboid is temperature-dependent and shrinks from 2.9081(7) (294 K) to 2.8743(5) (100 K). The 1D polymeric compound [{Cu(μ2-Br)}(μ2-L1)] n (CP2) was isolated upon treatment of CuBr with L1 in MeCN solution. Likewise, treatment of L1 with CuCl in a 1:1 ratio results in formation of the unusual 1D CP [{Cu(μ2-Cl)}(μ2-L1)] n (CP3). In contrast to CP1 incorporating dinuclear Cu(μ2-I)2Cu units as connection nodes, the isolated Cu atoms of CP2 and CP3 are bridged by a single μ2-Br or μ2-Cl ligand giving rise to infinite [Cu(μ2-X)Cu] n ribbons. Reaction of ferrocenecarbaldehyde with 1,2-ethanedithiol affords the crystallographically characterized ferrocenyl-dithiolane Fc-C(H)S2C2H4 (L2). L2 was used as organometallic dithioether ligand to assemble, upon treatment with CuI, the original luminescent 1D CP [{Cu2(μ4-I)(μ2-I)}(μ2-L2)] n (CP4), in which both S atoms of one L2 molecule span two copper centers of a meander-shaped infinite (CuI) n ribbon. Upon reaction of L2 with CuBr in a 1:2 ratio, the discrete tetranuclear cluster [{Cu4(μ2-Br)2(μ3-Br)2}(μ2-L2)2(MeCN)2] (CL1) is formed.

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Acknowledgements

We are grateful to the CNRS and the Ministère de la Recherche et Technologie for financial support and the region of Franche-Comté for funding a Post-doc fellowship for A. Raghuvanshi (Grant RECH-MOB15-000017). We warmly thank Ms. V. Moutarlier for her help with the powder X-ray measurements. We are also expressing our gratitude to KRG, Kurdistan Regional Government, and the Ministry of Higher Education and Scientific Research for their financial support to N. J. Dargallay. C. Strohmann and L. Knauer thank the Deutsche Forschungsgemeinschaft DFG for financial support and the Fonds der Chemischen Industrie (FCI) for a scholarship awarded to L. Knauer.

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Authors and Affiliations

  1. Institut UTINAM UMR CNRS 6213, Université Bourgogne Franche-Comté, 25030, Besançon, France

    Abhinav Raghuvanshi, Nakaw J. Dargallay, Michael Knorr & Lydie Viau

  2. Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44227, Dortmund, Germany

    Lena Knauer & Carsten Strohmann

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  1. Abhinav Raghuvanshi
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  2. Nakaw J. Dargallay
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  3. Michael Knorr
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Correspondence to Michael Knorr, Lydie Viau or Carsten Strohmann.

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This paper is dedicated to Prof. Pierre D. Harvey in honor to his scientific achievements.

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Raghuvanshi, A., Dargallay, N.J., Knorr, M. et al. 1,3-Dithiolane and 1,3-Ferrocenyl-dithiolane as Assembling Ligands for the Construction of Cu(I) Clusters and Coordination Polymers. J Inorg Organomet Polym 27, 1501–1513 (2017). https://doi.org/10.1007/s10904-017-0610-0

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