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Two 3D Supramolecular Coordination Polymers Constructed from Aromatic Carboxylic Acids and Flexible Bis(thiabendazole) Ligands

  • Xiao-Xue Zhao
  • Zeng-Chuan Hao
  • Suo-Xia Hou
  • Guang Hua CuiEmail author
Article

Abstract

Two coordination polymers (CPs), [Zn(L1)(H2bta)] (1) and [Co(L2)(ndc)]·0.75H2O (2), (L1 = 1,6-(thiabendazole)hexane), L2 = 1,3-(thiabendazole)propane, H4bta = 1,2,4,5-benzenetetracarboxylic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized. Single crystal X-ray diffraction analyses reveal that CP 1 and CP 2 feature 1D infinite zigzag and “Ω”-like chains, and further extend into 3D supramolecular framework by O–H⋯O and C–H⋯O hydrogen bonding interactions, respectively. Furthermore, the luminescence properties, thermal stability, and catalytic degradation of methyl orange in a Fenton-like process are also investigated in detail.

Keywords

Bis(thiabendazole) Cobalt(II) Coordination polymer Crystal structure Zinc(II) 

Notes

Acknowledgements

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299).

Supplementary material

10904_2017_538_MOESM1_ESM.docx (347 kb)
Supplementary material 1 (DOCX 346 KB)

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • Xiao-Xue Zhao
    • 1
  • Zeng-Chuan Hao
    • 1
  • Suo-Xia Hou
    • 1
  • Guang Hua Cui
    • 1
    Email author
  1. 1.College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic MaterialsNorth China University of Science and TechnologyTangshanPeople’s Republic of China

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