White Light Emitting EuIII and TbIII Doped Lanthanide Coordination Polymers Based on in Situ Formed Nitrilotriacetic Anion

Article

Abstract

Three 2D lanthanide coordination polymers of in situ formed nitrilotriacetic anion (NTA3−) have been hydrothermally synthesized with N-(2-carbamoylmethyl) iminodiacetic acid (H2ADA) as starting material. The photoluminescence properties as well as the energy-transfer behavior of the resulted coordination polymers are studied in detail and the investigations reveal that both EuIII and TbIII complexes show intense emissions characteristic of EuIII and TbIII ion under irradiation of 399 nm. Considering the blue-emission of compound GdIII and the intense emission of EuIII and TbIII compounds, we afforded EuIII and TbIII doped white light emitting materials by the different combination of the doped EuIII and TbIII concentrations.

Keywords

In situ hydrolysis Lanthanide coordinatiom polymer Luminescence properties White light emitting materials 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grants 21161011 and 21661019).

Supplementary material

10904_2017_526_MOESM1_ESM.tif (37 kb)
Supplementary material 1 (TIF 37 KB)
10904_2017_526_MOESM2_ESM.tif (38 kb)
Supplementary material 2 (TIF 37 KB)
10904_2017_526_MOESM3_ESM.tif (37 kb)
Supplementary material 3 (TIF 36 KB)

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.School of Chemical and Biological EngineeringLanzhou Jiaotong UniversityLanzhouChina

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