A Three-Dimensional Samarium Coordination Polymer with Benzene-1,2,4,5-tetracarboxylic Acid, Synthesis, Characterization and Thermal Decomposition to Sm2O3 Nanoparticles

  • Masoumeh Tabatabaee
  • Reza Mohammadinasab
  • Mehran Aghaie
Article
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Abstract

A treatment of benzene-1,2,4,5-tetracarboxylic acid (btcH4) and pyridine-2,3-dicarboxylic acid (pydcH2) with Sm(NO3)3·6H2O led to the formation of a new three-dimentional samarium(III) coordination polymer (just with btcH4),{[Sm(btcH2)0.5(btc)0.5(H2O)]·2H2O}∞ (1). Compound 1 was characterized by infrared spectroscopy, elemental analyses as well as by X-ray diffraction studies. The results of the single-crystal X-ray diffraction analyses reveal that compound is a 3D coordination polymer. The polymeric network of 1 contains Sm(III) ions bridged by btcH2 2− and btc4− ions. Each four-dentate btcH22− ion is connected to four Sm3+ ions through the four oxygen atoms of two deprotonated carboxyl groups and btc4− is coordinated to six Sm3+ ions as tree-dentate coordination through the four carboxylate groups. btc4− is also connected to two additional Sm3+ ions through the oxygen atoms. Samarium(III) ion is nine coordinated by oxygen atoms of two different btcH2 2−, two btc4− ligands and one water molecule. Many hydrogen bonds of the O–H···O type are also present in the crystal structure of 1 and assemble the polymeric chains and the co-crystallized water molecules into a 3D architecture. The coordination polymer 1 was used for the preparation of the Sm2O3 nanoparticles. Synthesized Sm2O3 nanoparticles were characterized by infrared spectroscopy, powder X-ray diffraction (PXRD) and scanning electron microscopy. The body- centered cubic structure of Sm2O3 was determined by PXRD.

Keywords

Samarium coordination polymer Sm2O3 nano-particles Benzene-1,2,4,5-tetracarboxylic acid 
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Notes

Acknowledgments

This research was supported by the Islamic Azad University, Science and Research Branch and as well as Islamic Azad University, Yazd branch.

References

  1. 1.
    Y. Yan, J. Huang, Coord. Chem. Rev. 254, 1072 (2010)CrossRefGoogle Scholar
  2. 2.
    S.-I. Noroa, S. Kitagawa, T. Akutagawa, T. Nakamura, Prog. Polym. Sci. 34, 240 (2009)CrossRefGoogle Scholar
  3. 3.
    G.A. Farnum, D.P. Martin, R.M. Supkowski, R.L. LaDuca, J. Mol. Struct. 927, 101 (2009)CrossRefGoogle Scholar
  4. 4.
    R. Carballo, B. Covelo, E. García-Martínez, A.B. Lago, E.M. Vázquez-López, Polyhedron 28, 923 (2009)CrossRefGoogle Scholar
  5. 5.
    K.M. Blake, G.A. Farnum, L.L. Johnston, R.L. LaDuca, Inorg. Chim. Acta 363, 88 (2010)CrossRefGoogle Scholar
  6. 6.
    Y.-Q. Zheng, X.-Y. Han, H.-L. Zhu, Polyhedron 29, 911 (2010)CrossRefGoogle Scholar
  7. 7.
    M. Tabatabaee, V. Razavimahmoudabadi, B.-M. Kukovec, M. Ghassemzadeh, B. Neumuller, J. Inorg. Organomet. Polym. 21, 450 (2011)CrossRefGoogle Scholar
  8. 8.
    D.-C. Zhong, H.-B. Guo, J.-H. Deng, Q. Chen, X.-Z. Luo, CrystEngComm 17, 3519 (2015)CrossRefGoogle Scholar
  9. 9.
    X.X. Hu, J.Q. Xu, P. Cheng, X.Y. Chen, X.B. Cui, J.F. Song, G.D. Yang, T.G. Wang, Inorg. Chem. 43, 2261 (2004)CrossRefGoogle Scholar
  10. 10.
    R. Murugavel, D. Krishnamurthy, M. Sathiyendiran, J. Chem. Soc., Dalton Trans. 34 (2002)Google Scholar
  11. 11.
    C.D. Wu, C.Z. Lu, W.B. Yang, S.F. Lu, H.H. Zhuang, J.S. Huang, Eur. J. Inorg. Chem. 4, 797 (2002)CrossRefGoogle Scholar
  12. 12.
    R. Cao, D. Sun, Y. Liang, M. Hong, K. Tatsumi, K.Q. Shi, Inorg. Chem. 41, 2087 (2002)CrossRefGoogle Scholar
  13. 13.
    M. Tabatabaee, M.A. Sharif, F. Vakili, S. Saheli, J. Rare, Earth 27, 356 (2009)CrossRefGoogle Scholar
  14. 14.
    L. Pan, N.W. Zheng, Y.G. Wu, S. Han, R.Y. Yang, X.Y. Huang, J. Li, Inorg. Chem. 40, 828 (2001)CrossRefGoogle Scholar
  15. 15.
    N. Soltanzadeh, A. Morsali, Polyhedron 28, 1343 (2009)CrossRefGoogle Scholar
  16. 16.
    H. Sadeghzadeh, A. Morsali, P. Retailleau, Polyhedron 29, 925 (2010)CrossRefGoogle Scholar
  17. 17.
    J. Gao, Y. Zhao, W. Yang, J. Tian, F. Guan, Y. Ma, J. Hou, J. Kang, Y. Wang, Mater. Chem. Phys. 77, 65 (2002)CrossRefGoogle Scholar
  18. 18.
    I. Gur, N.A. Fromer, M.L. Geier, A.P. Alivisatos, Science 310, 462 (2005)CrossRefGoogle Scholar
  19. 19.
    M. Law, L.E. Greene, J.C. Johnson, R. Saykally, P.D. Yang, Nat. Mater. 4, 455 (2005)CrossRefGoogle Scholar
  20. 20.
    A. Rosengren, B. Johansson, Phys. ReV. B 26, 3068 (1982)CrossRefGoogle Scholar
  21. 21.
    K. Kendall, Nature 404, 233 (2000)CrossRefGoogle Scholar
  22. 22.
    T.-D. Nguyen, D. Mrabet, T.-O. Do, J. Phys. Chem. C 112, 15226 (2008)CrossRefGoogle Scholar
  23. 23.
    Y.-S. Song, B. Yan, Inorg. Chim. Acta 358, 191 (2005)CrossRefGoogle Scholar
  24. 24.
    G.-Y. Zhou, G.-R. Wu, Z.-Y. Deng, X.-T. Chen, Acta Cryst. E64, m1348 (2008)Google Scholar
  25. 25.
    L. Zhao, S. Lin, S. Shen, J. Tang, Inorg. Chem. 14, 1928 (2011)Google Scholar
  26. 26.
    M. Tabatabaee, A. Gholamighavamabad, E. Khabiri, M. Parvez, J. Inorg. Organomet. Polym. 21, 627 (2011)CrossRefGoogle Scholar
  27. 27.
    M. Tabatabaee, R. Mohammad Hoseini, M. Parvez, Synth. React. Inorg. Met.-Org. Nano-Metal 44, 775 (2014)CrossRefGoogle Scholar
  28. 28.
    M. Tabatabaee, B.M. Kukovec, M. Kazeroonizadeh, Polyhedron 30, 1114 (2011)CrossRefGoogle Scholar
  29. 29.
    M. Tabatabaee, R. Mohamadinasab, K. Ghaini, H.R. Khavasi, Bull. Chem. Soc. Ethiop. 24, 401 (2010)CrossRefGoogle Scholar
  30. 30.
    R. Mohammadinasab, M. Tabatabaee, B.-M. Kukovec, H. Aghaie, Inorg. Chim. Acta 405, 368 (2013)CrossRefGoogle Scholar
  31. 31.
    M. Tabatabaee, S. Amjad, S. Tabatabaei, K. Molĉanov, Synth. React. Inorg. Met.-Org. Nano-Metal 44, 507 (2014)CrossRefGoogle Scholar
  32. 32.
    B.A. Bruker, APEX2, SAINT & SADABS (Bruker AXS Inc., Madison, 2007)Google Scholar
  33. 33.
    G.M. Sheldrick, Acta Cryst. A64, 112 (2008)CrossRefGoogle Scholar
  34. 34.
    Y.G. Sun, X. Song, L. Wang, W. Yu, Y.Q. Wang, G. Xiong, M.Y. Guo, E.J. Gao, Russ. J. Coord. Chem. 37, 312 (2011)CrossRefGoogle Scholar
  35. 35.
    M. Rafizadeh, V. Amani, Et Iravani, B. Neumülle, Z. Anorg. Allg. Chem. 631, 952 (2005)CrossRefGoogle Scholar
  36. 36.
    S.V. Ganesan, S. Natarajan, J. Chem. Sci. 116, 65 (2004)CrossRefGoogle Scholar
  37. 37.
    G.B. Deacon, R.J. Philips, Coord. Chem. Rev. 33, 227 (1980)CrossRefGoogle Scholar
  38. 38.
    K. Nakamoto, Infrared and Raman spectra of inorganic and coordination compounds, 4th edn. (Wiley Interscience, New York, 1986)Google Scholar
  39. 39.
    W. Zhou, Y. Xu, L. Han, D. Zhu, Dalton Trans. 39, 3681 (2010)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Masoumeh Tabatabaee
    • 1
  • Reza Mohammadinasab
    • 2
  • Mehran Aghaie
    • 3
  1. 1.Department of ChemistryIslamic Azad University, Yazd BranchYazdIran
  2. 2.Department of ChemistryIslamic Azad University, Science and Research BranchTehranIran
  3. 3.Department of ChemistryIslamic Azad University, North Tehran BranchTehranIran

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