Synthesis, Crystal Structure and Antitumor Activity of Ca(II) Coordination Polymer Based on 1,5-Naphthalenedisulfonate

Article
First Online:
Received:
Accepted:

Abstract

A novel Ca(II) coordination polymer, [CaL(H2O)2] n (L = 1,5-naphthalenedisulfonate), was synthesized by reaction of calcium perchlorate with 1,5-naphthalenedisulfonic acid sodium in CH3CH2OH/H2O. It was characterized by elemental analysis, IR, 1HNMR and thermal analysis. X-ray crystallographic reveals that the Ca(II) coordination polymer belongs to triclinic system, with space group P-1. The geometry of the Ca(II) ion is a distorted CaO6 octahedron coordination environment, arising from its coordination by two water molecules, and four oxygen atoms from two l ligands. The Ca(II) ions are linked through the O atoms of 1,5-naphthalenedisulfonate ligands to form 1D chain structure. And then a 2D layered structure is constructed by hydrogen bonds and π–π stacking. The antitumor activity of 1,5-naphthalenedisulfonic acid sodium ligand and its Ca(II) coordination polymer against human hepatoma smmc-7721 cell line and human lung adenocarcinoma A549 cell line have been investigated.

Keywords

1,5-Naphthalenedisulfonate Ca(II) coordination polymer Synthesis Crystal structure Antitumor activity 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgments

The authors would like to thank the National Natural Science Foundation of China (Nos. 21171132 and 20671073), the Promotive Research Fund for Excellent Young and Middle-aged Scientisits of Shandong Province (2010BSA07004) and Science Foundation of Weifang University.

References

  1. 1.
    Z.H. Li, L.P. Xue, L. Wang, S.T. Zhang, B.T. Zhao, Inorg. Chem. Commun. 27, 119 (2013)CrossRefGoogle Scholar
  2. 2.
    Y.J. Mu, Y.J. Song, C. Wang, H.W. Hou, Y.T. Fan, Inorg. Chim. Acta 365, 167 (2011)CrossRefGoogle Scholar
  3. 3.
    N.L. Rosi, J. Eckert, M. Eddaoudi, D.T. Vodak, J. Kim, M. O’Keefe, O.M. Yaghi, Science 300, 1127 (2003)CrossRefGoogle Scholar
  4. 4.
    L. Zhao, G.F. Xu, J. Tang, J. Mol. Struct. 979, 160 (2010)CrossRefGoogle Scholar
  5. 5.
    R.E. Mewis, S.J. Archibald, Coord. Chem. Rev. 254, 1686 (2010)CrossRefGoogle Scholar
  6. 6.
    D. Saha, R. Sen, T. Maity, S. Koner, Dalton Trans. 41, 7399 (2012)CrossRefGoogle Scholar
  7. 7.
    X.S. Tai, N. Wei, D.H. Wang, Materials 5, 558 (2012)CrossRefGoogle Scholar
  8. 8.
    X.S. Tai, Y.M. Feng, F.Y. Kong, D.Q. Wang, M.Y. Tan, Chinese. J. Inorg. Chem. 24, 831 (2008)Google Scholar
  9. 9.
    X.S. Tai, D. Wang, N. Tang, Asian J. Chem. 25, 1953 (2013)Google Scholar
  10. 10.
    X.S. Tai, S.Y. Chu, C.Y. Tang, Asian J. Chem. 25, 1913 (2013)Google Scholar
  11. 11.
    X.S. Tai, D.F. Wang, Z.B. Zhao, Chinese. J. Inorg. Chem. 26, 1490 (2008)Google Scholar
  12. 12.
    G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Solution (University of GÖttingen, GÖttingen, 1997)Google Scholar
  13. 13.
    G.M. Sheldrick, SHELXTL-97, Program for Crystal Structure Refinement (University of GÖttingen, GÖttingen, 1997)Google Scholar
  14. 14.
    N. Dodoff, K. Grancharow, R. Gugova, N. Spassovska, J. Inorg. Biochem. 54, 221 (1994)CrossRefGoogle Scholar
  15. 15.
    W.J. Geary, Coord. Chem. Rev. 7, 107 (1971)CrossRefGoogle Scholar
  16. 16.
    K. Nakamoto, Infrared and Ramen Spectra of Inorganic and Coordination Compounds, 3rd end (John Wiley and Sons, New York, 1978)Google Scholar
  17. 17.
    G. Demirtas, N. Dege, H. İcbudak, Ö. Yurdakul, O. Büyükgüngör, J. Inorg. Organomet. Polym. 22, 671 (2012)CrossRefGoogle Scholar
  18. 18.
    X.S. Tai, D.H. Wang, W.H. Zhao, Asian J. Chem. 25, 4427 (2013)Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringWeifang UniversityWeifangChina
  2. 2.Department of ChemistryQinghai Normal UniversityXiningChina

Personalised recommendations