Polycatenated Bilayer Structure Containing Honeycomb-like 63 Layers

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Abstract

A new luminescent Zn(II) compound, [Zn2(IN)3(bpy)0.5(CH3COO)]·2(DMA) (1, IN = isonicotinate, bpy = 4,4′-bipyridine, DMA = N,N-dimethylacetamide), was synthesized under solvothermal condition and structurally characterized by single crystal X-ray diffraction. Compound 1 features a (3,4)-connected bilayer structure with honeycomb-like 63 layers and bpy pillars. Each individual bilayer is catenated with two adjacent bilayers, giving rise to a rare 2D + 2D → 3D polycatenation motif.

Keywords

Solvothermal synthesis Metal-organic framework Polycantenation Luminescence 
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Notes

Acknowledgments

This work was supported by NSFC (21103189, U1162117), NSF of Fujian Province (2010J05039), Beijing Nova Program (Grant No. Z11111005450000) and Program for New Century Excellent Talents in University (NCET-11-0732).

Supplementary material

10904_2012_9815_MOESM1_ESM.doc (221 kb)
Supplementary material 1 (DOC 221 kb)

References

  1. 1.
    G. Férey, Chem. Soc. Rev. 37, 191 (2008)CrossRefGoogle Scholar
  2. 2.
    D.M. D’Alessandro, B. Smit, J.R. Long, Angew. Chem. Int. Ed. 49, 6058 (2010)CrossRefGoogle Scholar
  3. 3.
    J.-R. Li, R.J. Kuppler, H.-C. Zhou, Chem. Soc. Rev. 38, 1477 (2009)CrossRefGoogle Scholar
  4. 4.
    H.X. Zhang, F. Wang, H. Yang, Y.X. Tan, J. Zhang, X. Bu, J. Am. Chem. Soc. 133, 11884 (2011)CrossRefGoogle Scholar
  5. 5.
    F. Wang, Z.S. Liu, H. Yang, Y.X. Tan, J. Zhang, Angew. Chem. Int. Ed. 50, 450 (2011)CrossRefGoogle Scholar
  6. 6.
    O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)CrossRefGoogle Scholar
  7. 7.
    S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)CrossRefGoogle Scholar
  8. 8.
    X. Lin, J. Jia, X. Zhao, K.M. Thomas, A.J. Blake, G.S. Walker, N.R. Champness, P. Hubberstey, M. Schröder, Angew. Chem. Int. Ed. 45, 7358 (2006)CrossRefGoogle Scholar
  9. 9.
    Y. Liu, F. Boey, L.L. Lao, H. Zhang, X. Liu, Q. Zhang, Chem. Asian J. 6, 1004 (2011)CrossRefGoogle Scholar
  10. 10.
    B.-L. Chen, S.-G. Xiang, G.-D. Qian, Acc. Chem. Res. 43, 1115 (2010)CrossRefGoogle Scholar
  11. 11.
    B. Kesanli, W. Lin, Chem. Commun. 40, 2284 (2004)CrossRefGoogle Scholar
  12. 12.
    C.D. Wu, A. Hu, L. Zhang, W. Lin, J. Am. Chem. Soc. 127, 8940 (2005)CrossRefGoogle Scholar
  13. 13.
    L. Ma, C. Abney, W. Lin, Chem. Soc. Rev. 38, 1248 (2009)CrossRefGoogle Scholar
  14. 14.
    H. Wu, J. Yang, Y.Y. Liu, J.F. Ma, Cryst. Growth Des. 12, 2272 (2012)CrossRefGoogle Scholar
  15. 15.
    S.J. Wang, L. Li, J.Y. Zhang, X.C. Yuan, C.Y. Su, J. Mater. Chem. 21, 7098 (2011)CrossRefGoogle Scholar
  16. 16.
    L. Carlucci, G. Ciani, D.M. Proserpio, Cryst. Eng. Commun. 5, 269 (2003)CrossRefGoogle Scholar
  17. 17.
    J. Liu, Y.X. Tan, F. Wang, Y. Kang, J. Zhang, Cryst. Eng. Commun. 14, 789 (2012)CrossRefGoogle Scholar
  18. 18.
    J. Zhang, Y.C. Shen, Y.Y. Qin, Z.J. Li, Y.G. Yao, Cryst. Eng. Commun. 9, 636 (2007)CrossRefGoogle Scholar
  19. 19.
    S.M. Chen, J. Zhang, C.Z. Lu, Cryst. Eng. Commun. 9, 390 (2007)CrossRefGoogle Scholar
  20. 20.
    X. Zhang, Z.J. Li, Y.Y. Qin, Y.G. Yao, Inorg. Chem. Commun. 15, 1 (2012)CrossRefGoogle Scholar
  21. 21.
    X.X. Xu, X. Zhang, X.X. Liu, L.S. Wang, E.B. Wang, Cryst. Eng. Commun. 14, 3264 (2012)CrossRefGoogle Scholar
  22. 22.
    L. Qin, J.-S. Hu, L.-F. Huang, Y.-Z. Li, Z.-J. Guo, H.-G. Zheng, Cryst. Growth Des. 10, 4176 (2010)CrossRefGoogle Scholar
  23. 23.
    G.M. Sheldrick, SADABS (University of Göttingen, Göttingen, Germany, 1996)Google Scholar
  24. 24.
    G.M. Sheldrick, SHELXTL-97: Program for Refining Crystal Structure Refinement (University of Göttingen, Germany, 1997)Google Scholar
  25. 25.
    J.L.C. Rowsell, O.M. Yaghi, Microporous Mesoporous Mater. 73, 3 (2004)CrossRefGoogle Scholar
  26. 26.
    O.M. Yaghi, C.E. Davis, G. Li, H. Li, J. Am. Chem. Soc. 119, 2861 (1997)CrossRefGoogle Scholar
  27. 27.
    V.A. Blatov, A.P. Shevchenko, V.N. Serezhkin, Acta Crystallogr. A51, 909 (1995)Google Scholar
  28. 28.
    V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, Cryst. Eng. Commun. 6, 377 (2004)CrossRefGoogle Scholar
  29. 29.
    V.A. Blatov, D.M. Proserpio, Acta Cryst. A65, 202 (2009)Google Scholar
  30. 30.
    Q.Y. Liu, L. Xu, Cryst. Eng. Commun. 7, 87 (2005)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum (Beijing)BeijingPeople’s Republic of China
  2. 2.Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouPeople’s Republic of China

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