Synthesis and Characterization of New Zinc(II) Coordination Polymer with a Flexible Hetro-coordination Ligand via In Situ Reaction as a New Precursor for Zinc(II) Oxide Nano-sphere Particles

  • Mohammad Sadegh Yazdan Parast
  • Ali Morsali


A new coordination polymer, [Zn3(tza)3(H2O)3] n (1) which H2tza = 1H-tetrazolate-5-acetic acid has been synthesized and characterized by IR spectroscopy, elemental analysis X-ray crystallography. The single-crystal X-ray data of compound 1 show existence of three different ZnII ion with different coordination spheres, hexagonal, pyramidal and pentagonal. This coordination polymer used as a precursor for preparation of zinc(II) oxide nano-particles. Nano-particles were characterized by powder X-ray powder diffraction and the its morphology characterized by scanning electron microscope.


Zinc(II) coordination polymer Nanostructure Zinc(II) oxide 



Support of this investigation by Tarbiat Modares University is gratefully acknowledged.


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© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of SciencesTarbiat Modares UniversityTehranIslamic Republic of Iran

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