Synthesis and Characterization of New Zinc(II) Coordination Polymer with a Flexible Hetro-coordination Ligand via In Situ Reaction as a New Precursor for Zinc(II) Oxide Nano-sphere Particles

Article

Abstract

A new coordination polymer, [Zn3(tza)3(H2O)3] n (1) which H2tza = 1H-tetrazolate-5-acetic acid has been synthesized and characterized by IR spectroscopy, elemental analysis X-ray crystallography. The single-crystal X-ray data of compound 1 show existence of three different ZnII ion with different coordination spheres, hexagonal, pyramidal and pentagonal. This coordination polymer used as a precursor for preparation of zinc(II) oxide nano-particles. Nano-particles were characterized by powder X-ray powder diffraction and the its morphology characterized by scanning electron microscope.

Keywords

Zinc(II) coordination polymer Nanostructure Zinc(II) oxide 

Notes

Acknowledgments

Support of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of SciencesTarbiat Modares UniversityTehranIslamic Republic of Iran

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