Complexes Containing N-(2-hydroxyethyl)-ethylenediamine with Tetracyanometallate (II): Synthesis, IR Spectra, Thermal Behavior, Crystal Structure, Magnetic Properties and Catalysis

  • Ahmet Karadağ
  • Ayşegül Şenocak
  • Yusuf Yerli
  • Ertan Şahin
  • Ramazan Topkaya
Article
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Abstract

Two novel cyano-bridged Ni2+ and Cu2+ compounds, {[M2+(hydeten)2(μ-CN)2Ni(CN)2] n , M2+ = Ni2+ (c1) and Cu2+ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that Cu2+ was located in tetragonal distorted octahedral sites (D 4h ) and the ground state of the paramagnetic electron was \( d_{{ x^{2} - y^{2} }} \). The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects.

Keywords

Tetracyanometallate(II) N-(2-hydroxyethyl)-ethylenediamine Thermal behavior EPR Magnetic susceptibly Catalysis 
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Notes

Acknowledgments

This study was supported by the Scientific and Technical Research Council of Türkiye (TÜBİTAK, Grant TBAG-104T205). The authors are grateful to Professor İsmail Özdemir and Professor Nevin Gürbüz (Inönü University) for the catalysis in the study.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Ahmet Karadağ
    • 1
  • Ayşegül Şenocak
    • 1
  • Yusuf Yerli
    • 2
  • Ertan Şahin
    • 3
  • Ramazan Topkaya
    • 2
  1. 1.Department of Chemistry, College of Art and ScienceGaziosmanpaşa UniversityTokatTurkey
  2. 2.Department of PhysicsGebze Institute of TechnologyKocaeliTurkey
  3. 3.Department of Chemistry, College of ScienceAtatürk UniversityErzurumTurkey

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