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Fabrication of Silver Nanoparticles and 3D Interpenetrated Coordination Polymer Nanorods from the Same Initial Reagents

  • Kamran Akhbari
  • Mahmood Hemmati
  • Ali Morsali
Communication

Abstract

Nanorods of the three-dimensional coordination polymer, [Ag2(μ 2-py-4-c)2] n (1) [py-4-c = pyridine-4-carboxylate], have been synthesized by sonochemical process. The single-crystal X-ray data of compound 1 shows the formation of a 3D interpenetrated silver(I) coordination polymer, which has agostic interactions around the silver(I) ions and two types of AgI ions with O2NAg1···O2H, N2 Ag2···O2H2 coordination spheres. Silver nanoparticles were fabricated from thermal decomposition of 1 nanorods. These nanostructures were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The thermal stability of 1 was studied by thermo gravimetric (TG) and differential thermal (DT) analysis.

Keywords

Interpenetrated coordination polymer Agostic interactions Nanostructure Sonochemical 

Notes

Acknowledgment

Supporting of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of SciencesTarbiat Modares UniversityTehranIslamic Republic of Iran
  2. 2.Division of Polymer Science and TechnologyResearch Institute of Petroleum Industry (RIPI)TehranIslamic Republic of Iran

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