Advertisement

A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline

  • Guang-Xiang LiuEmail author
  • Xiao-Chun Zha
  • Yan Wang
  • Sadafumi Nishihara
  • Xiao-Ming Ren
Communication

Abstract

A new chiral Cu(II) complex, Cu3(phen)3(H2O)(BTA)2·13H2O (1) (H3BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ 2-H2O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.

Graphical Abstract

A new chiral Cu(II) complex, Cu3(phen)3(H2O)(BTA)2·13H2O (1) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex shows a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated.

Keywords

Copper (II) complex Carboxylate Nonlinear optical property Magnetic property 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 20971004, 20901004), the Key Project of Chinese Ministry of Education (No. 210102) and the Natural Science Foundation of Educational Commission of Anhui Province of China (No. KJ2010A229).

References

  1. 1.
    L.J. Prins, J. Huskens, F.D. Jong, P. Timmerman, Nature 398, 498 (1999)CrossRefGoogle Scholar
  2. 2.
    H.-Y. An, E.-B. Wang, D.-R. Xiao, Y.-G. Li, Z.-M. Su, L. Xu, Angew. Chem. Int. Ed. 45, 904 (2006)CrossRefGoogle Scholar
  3. 3.
    O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)CrossRefGoogle Scholar
  4. 4.
    S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 41, 1159 (2002)CrossRefGoogle Scholar
  5. 5.
    B. Kesanli, W.B. Lin, Coord. Chem. Rev. 246, 305 (2003)CrossRefGoogle Scholar
  6. 6.
    S. Zang, Y. Su, Y. Li, Z. Ni, Q. Meng, Inorg. Chem. 45, 174 (2006)CrossRefGoogle Scholar
  7. 7.
    O.R. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002)CrossRefGoogle Scholar
  8. 8.
    X.M. Chen, G.F. Liu, Chem. Eur. J 8, 4811 (2002)CrossRefGoogle Scholar
  9. 9.
    R.G. Xiong, X.Z. You, B.F. Abrahams, Z.L. Xue, C.M. Che, Angew. Chem. Int. Ed. 40, 4422 (2001)CrossRefGoogle Scholar
  10. 10.
    X.L. Wang, C. Qin, E.B. Wang, L. Xu, J. Mol. Struct. 737, 49 (2005)CrossRefGoogle Scholar
  11. 11.
    G.L.J.A. Rikken, E. Raupach, Nature 390, 49 (1997)CrossRefGoogle Scholar
  12. 12.
    S.R. Batten, R. Robson, Angew. Chem. Int. Ed. 37, 1460 (1998)CrossRefGoogle Scholar
  13. 13.
    H. Imai, K. Inoue, K. Kikuchi, Polyhedron 24, 2808 (2005)CrossRefGoogle Scholar
  14. 14.
    H. Kumagai, A.S. Markosyan, K. Inoue, Mol. Cryst. Liq. Cryst. 40, 97 (2000)CrossRefGoogle Scholar
  15. 15.
    E. Coronado, J.R. Galan-Mascaros, C.J. Gómez-García, J.M. Martinez-Agugo, Inorg. Chem. 40, 113 (2001)CrossRefGoogle Scholar
  16. 16.
    R. Andrés, M. Bissard, M. Gruselle, C. Train, J. Vaissermann, B. Malézieux, J.-P. Jamet, M. Verdaguer, Inorg. Chem. 40, 4633 (2001)CrossRefGoogle Scholar
  17. 17.
    D. Armentano, G.D. Munno, F. Lloret, A.V. Palii, M. Julve, Inorg. Chem. 41, 2007 (2002)CrossRefGoogle Scholar
  18. 18.
    M. Minguet, D. Luneau, E. Lhotel, V. Villar, C. Palusen, D.B. Amabilino, J. Veciana, Angew. Chem. Int. Ed. 40, 586 (2002)CrossRefGoogle Scholar
  19. 19.
    B. Kesanli, W. Lin, Coord. Chem. Rev. 246, 305 (2003)CrossRefGoogle Scholar
  20. 20.
    L. Pérez-García, D.B. Amabilino, Chem. Soc. Rev. 31, 342 (2002)CrossRefGoogle Scholar
  21. 21.
    M. Barquin, M.J. Gonzalez-Garmendia, L. Larrinaga, E. Pinilla, M.R. Torres, Z. Anorg. Allg. Chem. 631, 2151 (2005)CrossRefGoogle Scholar
  22. 22.
    K.-L. Pang, D. Guo, C.-Y. Duan, H. Mo, Q.-J. Meng, Inorg. Chem. 42, 5453 (2003)CrossRefGoogle Scholar
  23. 23.
    P. Talukder, S. Sen, S. Mitra, L. Dahlenberg, C. Desplanches, J.-P. Sutter, Eur. J. Inorg. Chem. 2006, 329 (2006)CrossRefGoogle Scholar
  24. 24.
    L.-M. Zheng, X.-Q. Wang, A.J. Jacobson, J. Solid State Chem. 152, 174 (2000)CrossRefGoogle Scholar
  25. 25.
    H. Uekusa, S. Ohba, T. Tokii, Acta Crystallogr. Sect. C 51, 625 (1995)CrossRefGoogle Scholar
  26. 26.
    M.S. Newman, H.S. Lowrie, J. Am. Chem. Soc. 76, 6196 (1954)CrossRefGoogle Scholar
  27. 27.
    O. Kahn, Molecular Magnetism (VCH Publishers. Inc, New York, 1993)Google Scholar
  28. 28.
    SAINT version 6.02a, Software Reference Manual (Bruker AXS Inc., Madison, 2002)Google Scholar
  29. 29.
    G.M. Sheldrick, SADABS. Program for Empirical Absorption Correction of Area Detector Data (University of Göttingen, Göttingen, 1996)Google Scholar
  30. 30.
    G.M. Sheldrick, SHELXS-97. Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997)Google Scholar
  31. 31.
    G.M. Sheldrick, SHELXL-97. Program for Crystal Structure Refinement (University of Göttingen, Göttingen, 1997)Google Scholar
  32. 32.
    Q. Ye, Y.M. Song, G.X. Wang, K. Chen, D.W. Fu, P.W.H. Chan, J.S. Zhu, S.D. Huang, R.G. Xiong, J. Am. Chem. Soc. 128, 6554 (2006)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Guang-Xiang Liu
    • 1
    • 2
    Email author
  • Xiao-Chun Zha
    • 1
  • Yan Wang
    • 1
    • 2
  • Sadafumi Nishihara
    • 3
  • Xiao-Ming Ren
    • 1
  1. 1.Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical EngineeringAnqing Normal UniversityAnqingPeople’s Republic of China
  2. 2.State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical EngineeringNanjing UniversityNanjingPeople’s Republic of China
  3. 3.Department of Physical Science, Graduate School of ScienceOsaka Prefecture UniversitySakaiJapan

Personalised recommendations