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Cu(II) and Zn(II)-Pyridine-2,3-Dicarboxylate Complexes with 2-Methylimidazole: Syntheses, Crystal Structures, Spectroscopic and Thermal Analyses

  • Fatih Semerci
  • Okan Zafer Yeşilel
  • Ertan Şahin
Article

Abstract

Two new Cu(II) and Zn(II)-pyridine-2,3-dicarboxylate (pydc) complexes with 2-methylimidazole (2-Meim), [Cu(pydc)(2-Meim)3]·H2O (1) and {[Zn(μ-pydc)(H2O)(2-Meim)]·H2O}n (2) have been synthesized and characterized by elemental, spectral (IR and UV–Vis.) and thermal analyses. The molecular structures of mononuclear (1) and polynuclear (2) complexes have been determined by the single crystal X-ray diffraction. Compound 1 crystallizes in the triclinic P − 1 space group, while compound 2 crystallizes in the monoclinic P21/c space group. The pyridine-2,3-dicarboxylate ligand acts in two different coordination modes; namely, bidentate-(N,O) for 1 and μ-tridentate-(N,O,O) for 2, the latter displaying a 1D polynuclear structure. The crystal packing of the complexes exhibit 3D supramolecular frameworks including channels by C–H···π, π···π, and N–H···O interactions. Water molecules occupy the channels by O–H···O hydrogen bonds.

Keywords

Pyridine-2,3-dicarboxylic acid Pyridine-2,3-dicarboxylate complexes 2-Methylimidazole complexes Thermal analysis 

Notes

Acknowledgments

This work was supported by the Eskişehir Osmangazi University by project No 200819042.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Fatih Semerci
    • 1
  • Okan Zafer Yeşilel
    • 1
  • Ertan Şahin
    • 2
  1. 1.Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskişehirTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesAtatürk UniversityErzurumTurkey

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