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One Dimensional Coordination Polymer of Nickel(II)-Squarate with N,N,N,N′-tetramethylethylenediamine, {[Ni(μ-sq)(H2O)2(tmen)]·H2O}n

  • Hakan Erer
  • Okan Zafer Yeşilel
  • Necmi Dege
  • Yelda Bingöl Alpaslan
Communication

Abstract

A novel 1D coordination polymer {[Ni(μ-sq)(H2O)2(tmen)]·H2O}n (H2sq = squaric acid and tmen = N,N,N′,N′ -tetramethylethylenediamine) has been synthesized and structurally characterized by X-ray crystallography. The spectral (IR and UV-vis.) and magnetic susceptibility are reported. The structure of the complex consists of the bidentate tmen ligand bound to Ni(II) center and a bridging squarate in the 1,3-bonding mode. The distorted octahedral geometry of Ni(II) is completed by two aqua ligands. The structure contains chains of squarato-O 1 ,O 3 -bridged polynuclear nickel(II) units held together by intermolecular hydrogen bonds interactions between water molecules and oxygen atoms of squarate ligand forming a novel R6 motif.

Keywords

Squarate complex N,N,N′,N′-Tetramethylethylenediamine complex Coordination polymer, Ni(II) complex 

Notes

Acknowledgments

The authors acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS–II diffractometer (purchased under grant F.279 of the University Research Fund).

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Hakan Erer
    • 1
  • Okan Zafer Yeşilel
    • 1
  • Necmi Dege
    • 2
  • Yelda Bingöl Alpaslan
    • 2
  1. 1.Faculty of Arts and Sciences, Department of ChemistryEskişehir Osmangazi UniversityEskisehirTurkey
  2. 2.Faculty of Arts and Sciences, Department of PhysicsOndokuz Mayis UniversitySamsunTurkey

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