Advertisement

Hetero-Metallic Coordination Polymers: Syntheses, Vibrational Spectra, Thermal Analyses and Crystal Structures of trans-[M(N-Meim)2Ni(μ–CN)4] n (M=Cu(II), Zn(II) and Cd(II))

  • Güneş Süheyla Kürkçüoğlu
  • Okan Zafer Yeşilel
  • İlkan Kavlak
  • Orhan Büyükgüngör
Article

Abstract

Three cyano bridged hetero-metallic complexes of general formula, trans-[M(N-Meim)2Ni(μ-CN)4] n (N-Meim=N-methylimidazole and M=Cu(II), Zn(II) or Cd(II)) have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal analyses and elemental analyses. The crystallographic analyses reveal that the complexes, [Cu(N-Meim)2Ni(μ-CN)4] n (1), [Zn(N-Meim)2Ni(μ-CN)4] n (2) and [Cd(N-Meim)2Ni(μ-CN)4] n (3), have polymeric 2D networks. In the complexes, four cyanide groups of [Ni(CN)4]2− coordinated to the adjacent M(II) ions and distorted octahedral geometries of complexes are completed by two nitrogen atoms of trans N-Meim ligands. Vibration assignments are given for all the observed bands and the spectral features also supported to the crystal structures of polynuclear complexes.

Keywords

Hetero-metallic complexes Cyano-bridged complexes Tetracyanonickelate(II) complexes N-Methylimidazole complexes 

Notes

Acknowledgment

This work has been supported by the Research Fund of Eskişehir Osmangazi University, project number 200719025. Raman spectra were recorded at Anadolu University, Department of Physics. The authors thank Prof. Dr. Mustafa Şenyel for support during the Raman spectra.

References

  1. 1.
    A.G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals (Academic Press, London, 1976)Google Scholar
  2. 2.
    K.A. Hofmann, F. Küspert, Z. Anorg, Allgem. Chem 15, 204 (1897)Google Scholar
  3. 3.
    J. Cernak, M. Orendac, I. Potocnak, J. Chomic, A. Orendacova, J. Skorsepa, A. Feher, Coord. Chem. Rev 224, 51 (2002)CrossRefGoogle Scholar
  4. 4.
    T. Iwamoto, in Comprehensive Supramolecular Chemistry, vol. 6, ed. by D.D. MacNicol, F. Toda, R. Bishop (Pergamon Press, Oxford, 1996). Chapter 19Google Scholar
  5. 5.
    T. Iwamoto, J. Incl. Phenom 24, 61 (1996)CrossRefGoogle Scholar
  6. 6.
    M. Kamper, M. Wagner, A. Weiss, Angew. Chem 91, 517 (1979)CrossRefGoogle Scholar
  7. 7.
    J. Cernak, K.A. Abboud, Acta Crystallogr C56, 783 (2000)Google Scholar
  8. 8.
    J. Cernak, J. Paharova, J. Skorsepa, W. Massa, Z. Anorg, Allg. Chem 628, 344 (2002)CrossRefGoogle Scholar
  9. 9.
    T. Hökelek, D. Ülkü, Acta Crystallogr C44, 832 (1988)Google Scholar
  10. 10.
    J. Cernak, I. Potocnak, J. Chomic, M. Dunaj-Jurco, Acta Crystallogr C46, 1098 (1990)Google Scholar
  11. 11.
    J. Cernak, J. Chomic, D. Baloghova, M. Dunaj-Jurco, Acta Crystallogr C44, 1902 (1988)Google Scholar
  12. 12.
    J. Lokaj, K. Gyerova, A. Sopkova, J. Sıvy, V. Kettnann, V. Vrabel, Acta Crystallogr C47, 2447 (1991)Google Scholar
  13. 13.
    A. Karadağ, A. Bulut, A. Şenocak, İ. Uçar, O. Büyükgüngör, J. Coord. Chem 60, 2035 (2007)CrossRefGoogle Scholar
  14. 14.
    A. Karadağ, İ. Önal, A. Şenocak, İ. Uçar, A. Bulut, O. Büyükgüngör, Polyhedron 27, 223 (2008)CrossRefGoogle Scholar
  15. 15.
    T. Iwamoto, J.L. Atwood, J.E.D. Davies, D.D. MacNicol, Inclusion Compounds, vol. 1 (Academic Press, London, 1984). Chapter 2Google Scholar
  16. 16.
    T. Iwamoto, in Inclusion Compounds, vol. 5, ed. by J.L. Atwood, J.E.D. Davies, D.D. MacNicol (Oxford University Press, Oxford, 1991). Chapter 6Google Scholar
  17. 17.
    S. Akyüz, A.B. Dempster, R.L. Morehouse, S. Suzuki, J.Mol. Struct 17, 105 (1973)CrossRefGoogle Scholar
  18. 18.
    G.S. Kürkçüoğlu, T. Hökelek, O.Z. Yeşilel, S. Aksay, Struct. Chem 19, 493 (2008)CrossRefGoogle Scholar
  19. 19.
    A. Sungur, S. Akyüz, J.E.D. Davies, J. Incl. Phenom 5, 491 (1987)CrossRefGoogle Scholar
  20. 20.
    J.T. Edsall, G. Felsenfeld, D.S. Goodman, F.R.N. Gurd, J. Am. Chem. Soc 76, 3034 (1954)CrossRefGoogle Scholar
  21. 21.
    Y. Nozaki, F.R.N. Gurd, R.H. Chen, J.T. Edsall, ibid 79, 2123 (1957)Google Scholar
  22. 22.
    G. Iwarsson, Acta Chem. Scand 27, 3523 (1973)CrossRefGoogle Scholar
  23. 23.
    B. Lenarcik, K. Kurdziel, Pol. J. Chem 55, 737 (1982)Google Scholar
  24. 24.
    H. Imai, H. Tamura, Bull. Chem. Soc. Jpn 64, 2077 (1991)CrossRefGoogle Scholar
  25. 25.
    C.C. Su, J.H. Chen, K.Y. Hwang, S.J. Liu, S.W. Wang, S.L. Wang, S.N. Liu, Inorg. Chim. Acta 196, 231 (1992)CrossRefGoogle Scholar
  26. 26.
    A. Turek, M. Olczak-Kobza, J. Therm. Anal 54, 133 (1998)CrossRefGoogle Scholar
  27. 27.
    Y.Q. Zheng, J.L. Liu, E.B. Ying, Z. Anorg, Allg. Chem 629, 673 (2003)CrossRefGoogle Scholar
  28. 28.
    J.B. Hodgson, G.C. Percy, D.A. Thornton, J. Mol. Struc 66, 81 (1980)CrossRefGoogle Scholar
  29. 29.
    Y. Tufan, N. Karacan, J.E.D. Davies, Vibr. Spectr 23, 51 (2000)CrossRefGoogle Scholar
  30. 30.
    Y. Tufan, J. Incl. Phenom 48, 131 (2004)CrossRefGoogle Scholar
  31. 31.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, İ. Kavlak, S. Kurtaran, O. Büyükgüngör, J. Org. Inorganometall. Poly. Mater. (2009). doi: 10.1007/s10904-009-9277-5
  32. 32.
    G.M. Sheldrick, SHELXS-97 and SHELXL-97. Program for Refinement of Crystal Structures (University of Göttingen, Germany, 1997)Google Scholar
  33. 33.
    Stoe & Cie (2002) X-Area (Version 1.18) and X-Red32 (Version 1.04) (Stoe & Cie, Darmstadt, Germany, 2001)Google Scholar
  34. 34.
    L.J. Farrugia, J. Appl. Crystallogr 30, 565 (1997)CrossRefGoogle Scholar
  35. 35.
    L.J. Farrugia, J. Appl. Crystallogr 32, 837 (1999)CrossRefGoogle Scholar
  36. 36.
    V.N. Sheinker, D.Ya. Movshovich, O.A. Osipov, A.D. Garnovskii, Z.H. Obshch, Khim 43, 2725 (1973)Google Scholar
  37. 37.
    C. Perchard, A. Novak, Spectrochim. Acta, Part A 23, 1953 (1967)CrossRefGoogle Scholar
  38. 38.
    F.R. Dollish, W.G. Fateley, F.F. Bentley, Characteristic Raman Frequencies of Organic Compounds (Wiley, New York, 1974), pp. 228–233Google Scholar
  39. 39.
    R.L. McCullough, L.H. Jones, G.A. Crosby, Spectrochim. Acta 16, 929 (1960)CrossRefGoogle Scholar
  40. 40.
    L.E. Orgel, An Introduction to Transition-Metal Chemistry (Methuen, London, 1967)Google Scholar
  41. 41.
    L.E. Orgel, J.D. Dunitz, Nature 179, 462 (1957)CrossRefGoogle Scholar
  42. 42.
    H. Irving, R.J.P. Williams, J. Chem. Soc. 3192 (1953)Google Scholar
  43. 43.
    G.J. Gainsford, N.F. Curtis, Aust. J. Chem 37, 1799 (1984)Google Scholar
  44. 44.
    S.Z. Shan, D. Guo, X.Y. Zhang, C.X. Du, Y. Zhu, R.N. Yang, Inorg. Chim. Acta 298, 57 (2000)CrossRefGoogle Scholar
  45. 45.
    H.Z. Kou, D.Z. Liao, P. Cheng, Z.H. Jiang, S.P. Yan, G.L. Wang, X.K. Yao, H.G. Wang, J. Chem. Soc., Dalton Trans. 1503 (1997)Google Scholar
  46. 46.
    H. Yuge, A. Mamada, M. Asai, S. Nishikiori, T. Iwamoto, J. Chem. Soc. Dalton Trans. 3195 (1995)Google Scholar
  47. 47.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, İ. Kavlak, O. Büyükgüngör, Struct. Chem 19, 879 (2008)CrossRefGoogle Scholar
  48. 48.
    M. Aygün, G. Utlu, A.G. Gökçe, S. Akyüz, S. Özbey, Acta Crystallogr C61, 117 (2005)Google Scholar
  49. 49.
    H. Yuge, C. Kim, T. Iwamoto, T. Kitazawa, Inorg. Chim. Acta 257, 217 (1997)CrossRefGoogle Scholar
  50. 50.
    A. Erdönmez, Ş. Işık, O. Büyükgüngör, S. Akyüz, G. Nardin, Spec. Lett 31, 1325 (1998)CrossRefGoogle Scholar
  51. 51.
    H. Yuge, T. Iwamoto, J. Chem. Soc. Dalton Trans. 1237 (1994)Google Scholar
  52. 52.
    D. Ghoshal, A.K. Ghosh, T.K. Maji, J. Ribas, G. Mostafa, E. Zangrando, N.R. Chaudhuri, Inorg. Chim. Acta 359, 593 (2006)CrossRefGoogle Scholar
  53. 53.
    Z. Smékal, I. Císatová, J. Mrozinski, Polyhedron 20, 3301 (2001)CrossRefGoogle Scholar
  54. 54.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, İ. Kavlak, O. Büyükgüngör, Z. Anorg, Allg. Chem 635, 175 (2008)Google Scholar
  55. 55.
    C. Kim, S. Lee, I. Suh, J. Chem. Crystallogr 34, 13 (2004)CrossRefGoogle Scholar
  56. 56.
    T. Soma, T. Iwamoto, Inorg. Chem 35, 1849 (1996)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Güneş Süheyla Kürkçüoğlu
    • 1
  • Okan Zafer Yeşilel
    • 2
  • İlkan Kavlak
    • 1
  • Orhan Büyükgüngör
    • 3
  1. 1.Faculty of Arts and Sciences, Department of PhysicsEskişehir Osmangazi UniversityEskişehirTurkey
  2. 2.Faculty of Arts and Sciences, Department of ChemistryEskişehir Osmangazi UniversityEskişehirTurkey
  3. 3.Faculty of Arts and Sciences, Department of PhysicsOndokuz Mayıs UniversitySamsunTurkey

Personalised recommendations