Numerical Modeling of the Ignition of Hydrogen–Oxygen Mixtures Under Nonequilibrium Conditions
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A numerical study has been made of the intensification of combustion in hydrogen-oxygen mixtures with a low-temperature nonequilibrium plasma, when the concentration of the active particles in the mixture (atoms, radicals, ions, and excited particles) is much higher than their equilibrium concentrations. Primary emphasis has been placed on the influence of higher-than-average concentrations of electronically excited O2(a 1Δg) molecules and O( 1Δ) atoms on the acceleration of the process of ignition. Electron-beam irradiation of the fuel mixture and the action of a high-voltage nanosecond discharge on it were selected for comparison of the efficiency of different types of plasma initiation of combustion.
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combustion excited oxygen kinetic mechanism induction time electron-beam irradiation gas dischargePreview
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- 1.H. Taguchi, H. Kobayashi, T. Kojima, A. Ueno, S. Imamura, M. Hongoh, and K. Harada, Research on hypersonic aircraft using pre-cooled turbojet engines, Acta Astronaut., 73, No. 1, 164–172 (2012).CrossRefGoogle Scholar
- 2.D. Cecere, A. Ingenito, E. Giacomazzi, L. Romagnosi, and C. Bruno, Hydrogen/air supersonic combustion for future hypersonic vehicles, Int. J. Hydrogen Energy, 36, No. 18, 11969–11984 (2011).CrossRefGoogle Scholar
- 3.S. Brieschenk, S. O’Byrne, and H. Kleine, Laser-induced plasma ignition studies in a model scramjet engine, Combust. Flame, 160, No. 1, 145–148 (2013).CrossRefGoogle Scholar
- 4.S. M. Starikovskaia, Plasma assisted ignition and combustion, J. Phys. D: Appl. Phys., 39, No. 16, R265–R299 (2006).CrossRefGoogle Scholar
- 5.A. I. Pushkarev and G. E. Remnev, Initiation of oxidation of hydrogen by a pulsed electron beam, Fiz. Goreniya Vzryva, 41, No. 3, 46–51 (2005).Google Scholar
- 6.T. Ombrello, S. H. Won, Y. Ju, and S. Williams, Flame propagation by plasma excitation of oxygen. Part II: Effect of O2(a 1Δg), Combust. Flame, 157, No. 10, 1916–1928 (2010).Google Scholar
- 7.N. A. Popov, Influence of nonequilibrium excitation on the ignition of hydrogen–oxygen mixtures, Teplofiz. Vys. Temp., 45, No. 2, 296–315 (2007).Google Scholar
- 8.A. S. Sharipov and A. M. Starik, Kinetic mechanism of CO–H2 system oxidation promoted by excited singlet oxygen molecules, Combust. Flame, 159, No. 1, 16–29 (2012).CrossRefGoogle Scholar
- 9.N. A. Popov, Effect of singlet oxygen O2(a 1Δg) molecules produced in a gas discharge plasma on the ignition of hydrogen–oxygen mixtures, Plasma Sources Sci. Technol., 20, No. 045002, 1–11 (2011).Google Scholar
- 10.G. Ya. Gerasimov and O. P. Shatalov, Kinetic mechanism of combustion of hydrogen–oxygen mixtures, Inzh.-Fiz. Zh., 86, No. 5, 929–936 (2013).Google Scholar
- 11.L. B. Ibragimova and O. P. Shatalov, Rate constants of reactions for study of the combustion of oxygen–hydrogen mixtures involving excited atoms O(1D) and O(1S) and molecules O2(b 1 S), O2(a 1Δ), and OH(A2 S) (2013). http://www.chemphys.edu.ru/media/files/2013-03-12-001.pdf.
- 12.N. Washida, H. Akimoto, and M. Okuda, Formation of singlet state molecular oxygen in the reaction of H + O2, J. Phys. Chem., 82, No. 1, 18–21 (1978).CrossRefGoogle Scholar
- 13.R. Atkinson, D. L. Baulch, R. A. Cox, J. N. Crowley, R. F. Hampson, and R. G. Hynes, Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I — gas phase reactions of Ox, HOx, NOx, and SOx species, Atmos. Chem. Phys., 4, No. 6, 1461–1738 (2004).CrossRefGoogle Scholar
- 14.I. D. Clark and R. P. Wayne, Collisional quenching of O2(1Δg), Proc. Roy. Soc. London A, 314, No. 1516, 111–127 (1969).CrossRefGoogle Scholar
- 15.K. H. Becker, W. Groth, and U. Schurath, The quenching of metastable O2(1Δg) and O2(1Σg +) molecules, Chem. Phys. Lett., 8, No. 3, 259–262 (1971).CrossRefGoogle Scholar
- 16.J. R. Podolske and H. S. Johnson, Rate of the resonant energy-transfer reaction between molecular oxygen O2(1Δg) and perhydroxyl (HOO), J. Phys. Chem., 87, No. 4, 628–634 (1983).CrossRefGoogle Scholar
- 17.J. T. Herron and D. S. Green, Chemical kinetics database and predictive schemes for nonthermal air plasma chemistry. Part II. Neutral species reactions, Plasma Chem. Plasma Process., 21, No. 3, 459–481 (2001).CrossRefGoogle Scholar
- 18.A. A. Konnov, Remaining uncertainties in the kinetic mechanism of hydrogen combustion, Combust. Flame, 152, No. 4, 507–528 (2008).CrossRefMathSciNetGoogle Scholar
- 19.R. F. Heidner, C. E. Gardner, T. M. El-Sayed, G. I. Segal, and J. V. V. Kasper, Temperature dependence of O2(1Δ)+O2(1Δ) and I(2P1/2)+O2(1Δ) energy pooling, J. Chem. Phys., 74, No. 10, 5618–5627 (1981).CrossRefGoogle Scholar
- 20.J. Shi and J. R. Barker, Kinetic studies of the deactivation of O2(1Σg +) and O(1D), Int. J. Chem. Kinet., 22, No. 12, 1283–1301 (1990).CrossRefGoogle Scholar
- 21.S. P. Sander, J. Abbatt, J. R. Barker, et al., Chemical kinetics and photochemical data for use in atmospheric studies. Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena (2011); http://jpldataeval.jpl.nasa.gov.
- 22.A. Burcat and B. Ruscic, Third Millennium Ideal Gas and Condensed Phase Thermochemical Database for Combustion with Updates from Active Thermochemical Tables, ANL-05/20 and TAE 960, Technion-IIT, Aerospace Eng. and Argonne National Laboratory, Chemistry Division (2005).Google Scholar
- 23.V. Ya. Basevich and A. A. Belyaev, Calculation of the increase in the velocity of a hydrogen-oxygen flame on additions of singlet oxygen, Khim. Fiz., 8, No. 8, 1124–1127 (1989).Google Scholar
- 24.S. H. Mousavipour and V. Saheb, Theoretical study on the kinetic and mechanism of H + HO2 reaction, Bull. Chem. Soc. Jpn., 80, No. 10, 1901–1913 (2007).CrossRefGoogle Scholar
- 25.A. Starik and A. Sharipov, Theoretical analysis of reaction kinetics with singlet oxygen molecules, Phys. Chem. Chem. Phys., 13, No. 36, 16424–16436 (2011).CrossRefGoogle Scholar
- 26.S. W. Mayer and L. Schieler, Activation energies and rate constants computed for reactions of oxygen with hydrocarbons, J. Phys. Chem., 72, No. 7, 2628–2631 (1968).CrossRefGoogle Scholar
- 27.P. Borrell and D. S. Richards, Quenching of singlet molecular oxygen O2(a 1Δg) and O2(b 1 Σg) by H, HCl and HBr, J. Chem. Soc. Faraday Trans. 2, 85, No. 9, 1401–1411 (1989).CrossRefGoogle Scholar
- 28.L. T. Cupitt, G. A. Takacs, and G. P. Glass, Reaction of hydrogen atoms and O2(1Δg), Int. J. Chem. Kinet., 14, No. 5, 487–497 (1982).CrossRefGoogle Scholar
- 29.V. Ya. Basevich and V. I. Vedeneev, Rate constant of the reaction H + O2(a 1Δg) = OH + O, Khim. Fiz., 4, No. 8, 1102–1106 (1985).Google Scholar
- 30.D. I. Slovetskii, Mechanisms of Chemical Reactions in a Nonequilibrium Plasma [in Russian], Nauka, Moscow (1980).Google Scholar
- 31.R. J. Kee, F. M. Rupley, E. Meeks, and J. A. Miller, Chemkin- III: A Fortran Chemical Kinetics Package for the Analysis of Gas-Phase Chemical and Plasma Kinetics, Technical Report SAND96-8218, Livermore, Sandia National Laboratories (1996).Google Scholar
- 32.V. V. Smirnov, O. M. Stel’makh, V. I. Fabelinskii, D. N. Kozlov, A. M. Starik, and N. S. Titova, On the influence of electronically excited oxygen molecules on combustion of hydrogen–oxygen mixture, J. Phys. D: Appl. Phys., 41, No. 19, 192001(6pp).Google Scholar
- 33.A. A. Chukalovsky, K. S. Klopovsky, M. A. Liberman, Y. A. Mankelevich, N. A. Popov, O. V. Proshina, and T. V. Rakhimova, Study of singlet delta oxygen O2(1Δg) impact on H2–O2 mixture ignition in flow reactor: 2D modeling, Combust. Sci. Technol., 184, Nos. 10–11, 1768–1786 (2012).CrossRefGoogle Scholar
- 34.C. Willis and A. W. Boyd, Excitation in the radiation chemistry of inorganic gases, Int. J. Radiat. Phys. Chem., 8, No. 1, 71–111 (1976).CrossRefGoogle Scholar
- 35.B. D. Sharpee and T. G. Slanger, O(1D2–3P2,1,0) 630.0, 636.4, 636.4, and 639.2 nm forbidden emission line intensity ratios measured in the Terrestrial nightglow, J. Phys. Chem. A, 110, No. 21, 6707–6710 (2006).CrossRefGoogle Scholar
- 36.A. D. Snyder, J. Robertson, D. L. Zanders, and G. B. Skinner, Shock tube studies of fuel-air ignition characteristics, Technical report AFAPL-TR-65-93, Air Force Aero-Propulsion Laboratory, Wright-Patterson (1965).Google Scholar
- 37.M. W. Slack, Rate coefficient for H + O2 + M = HO2 + M evaluated from shock tube measurements of induction times, Combust. Flame, 28, No. 1, 241–249 (1977).CrossRefGoogle Scholar
- 38.G. Y. Gerasimov, Ionizing-radiation ignition of a hydrogen–air mixture, High Energy Chem., 36, No. 6, 370–373 (2002).CrossRefMathSciNetGoogle Scholar
- 39.S. A. Bozhenkov, S. M. Starikovskaia, and A. Y. Starikovskii, Nanosecond gas discharge ignition of H2- and CH4-containing mixtures, Combust. Flame, 133, Nos. 1–2, 133–146 (2003).CrossRefGoogle Scholar
- 40.D. Dautzenberg, Gamma-radiolysis of hydrogen–oxygen mixtures. Part I. Influences of temperature, vessel wall, pressure and added gases (N2, Ar, H2) on the reactivity of H2/O2 mixtures, Radiat. Phys. Chem., 33, No. 1, 61–67 (1989).Google Scholar
- 41.A. K. Pikaev, Modern Radiation Chemistry: Radiolysis of Gases and Liquids [in Russian], Nauka, Moscow (1986).Google Scholar