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Preparation and Enhanced Photo-/Electro-Catalytic Activities of Polypyrrole Coating [CuMo12O40]6− POM Based MOF Composite

  • Jingwei Zhang
  • Jisheng ZhangEmail author
Original Paper
  • 7 Downloads

Abstract

A new polyoxometalates (POMs) based hybrid compound with helical chains, H4[Cu2(bpe)3](CuMo12O40) (Cu2CuMo12) (bpe = bis(4-pyridyl)ethylene), was synthesized by the reaction of Cu(NO3)2 (NH4)6Mo7O24 and bpe, and characterized by elemental analyses, IR, PXRD and X-ray single crystal diffraction, in which the Keggin-type [CuMo12O40]6− polyoxoanion was fabricated in suit. Moreover, to improve the photo-/electo-catalytic activities, the polypyrrole (PPy) coating Cu2CuMo12 composites (Cu2CuMo12/PPy-n) have been prepared and exhibited excellent photo- and electro-catalytic activities. More specifically, the photocatalytic decomposition rate of methylene blue (MB) using the Cu2CuMo12/PPy-2 as catalyst is 93.1% under the visible light, which is much larger than that of Cu2CuMo12 (13.1%). The electrochemical properties of Cu2CuMo12/PPy-2 exhibit similar redox behavior to the Cu2CuMo12, involving two-, four- and six-electron-reduced species for the reduction of nitrite.

Keywords

Polyoxometalates Metal–organic framework Helix Electrocatalytic activity Photocatalytic activity 

Notes

Acknowledgements

Financial support from Heilongjiang Provincial Health and Family Planning Commission on Scientific Research Project (2017-405).

Supplementary material

10876_2019_1710_MOESM1_ESM.docx (2.9 mb)
Supplementary material 1 (DOCX 3014 kb)
10876_2019_1710_MOESM2_ESM.cif (555 kb)
Supplementary material 2 (CIF 555 kb)
10876_2019_1710_MOESM3_ESM.pdf (260 kb)
Supplementary material 3 (PDF 259 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.The Institute of Applied InsectJiamusi UniversityJiamusiPeople’s Republic of China

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