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Synthesis, Structure and Magnetic Properties of a Fe(III) [24-azaMC-8] Azametallacrown Nanocluster with Diacylhydrazine Ligand

  • Sen-Da Su
  • Xiao-Ming Ou-Yang
  • Ke-Ke Guo
  • Qing-Mei Lin
  • Yan Li
  • Kai WangEmail author
  • Shu-Ying LuoEmail author
  • Fu-Pei LiangEmail author
Original Paper
  • 33 Downloads

Abstract

A novel Fe(III) cluster formulated as [\({\text{Fe}}^{\text{III}}_{8}\)(schhz)4(Py)6(H2O)2]∙2H2O (1) was synthesized by the hydrothermal reaction of FeCl2 and a symmetrical diacylhydrazine ligand N,N′-bissalicyl-1,3-cyclohexanedicarbohydrazide (H6schhz) in the presence of pyridine (Py) and pyrazine (Pz). It displays a nano-sized [24-MC-8] azametallacrown (azaMC) structure that eight Fe(III) ions are linked together by N–N bridges from four schhz6− ligands. To the best of our knowledge, it is the second case of Fe(III) [24-MC-8] azaMC up to now. The magnetic investigations reveal that the N–N bridges convey antiferromagnetic couplings between the Fe(III) centers in the system.

Keywords

Fe(III) azametallacrown Diacylhydrazine Magnetic properties 

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21771043 and 51572050), the Guangxi Natural Science Foundation (No. 2018GXNSFAA138123) and the Program of the Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi (No. GXYSXTZX2017-II-3).

Supplementary material

10876_2019_1545_MOESM1_ESM.docx (1 mb)
Supplementary material 1 (DOCX 1069 kb)
10876_2019_1545_MOESM2_ESM.cif (2.3 mb)
Supplementary material 2 (CIF 2336 kb)
10876_2019_1545_MOESM3_ESM.pdf (268 kb)
Supplementary material 3 (PDF 268 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and BioengineeringGuilin University of TechnologyGuilinChina
  2. 2.State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and PharmacyGuangxi Normal UniversityGuilinChina

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