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Journal of Cluster Science

, Volume 29, Issue 6, pp 1269–1274 | Cite as

Bifunctional (3,6)-Connected Gd(III) Metal–Organic Framework Material with Catalytic Properties for the Cyanosilylation Reaction and Anti-gastric Cancer Activity

  • Zhou-Feng Chen
  • Hai-Bo Xue
  • Lei-Ruo Wu
  • Rui-Fang Jin
Original Paper
  • 100 Downloads

Abstract

A new Gd(III) coordination polymer, namely [Gd(bpt)(H2O)(DMF)]n·3n(H2O) (1, H3bpt = biphenyl-3,4′,5-tricarboxylic acid, DMF = N,N-dimethylformamide), has been successfully synthesized under solvothermal conditions. In the structure of 1, the dinuclear [Gd2(COO)4] building subunits are connected by the bpt3− ligands into a 3D framework with (3,6)-connected flu-3,6-C2/c topology. Moreover, the catalytic performances of 1 and 1′ (desolvated sample) towards the cyanosilylation of benzaldehyde and its derivatives have been tested under mild conditions. The catalytic activity of 1′ is higher than that of compound 1, indicating that more open metal sites in coordination polymer is beneficial to the cyanosilylation reaction. In addition, in vitro anticancer activities of compounds 1 and 1′ (desolvated sample) on four human gastric cancer cells (MGC-803, SGC-790, MKN45 and AGS) were further determined.

Keywords

Gd(III) compound Biphenyl-3,4′,5-tricarboxylic acid Solvothermal reaction Cyanosilylation reaction Anti-gastric cancer activity 

Supplementary material

10876_2018_1445_MOESM1_ESM.doc (1.4 mb)
Supplementary material 1 (DOC 1476 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Zhou-Feng Chen
    • 1
  • Hai-Bo Xue
    • 1
  • Lei-Ruo Wu
    • 1
  • Rui-Fang Jin
    • 1
  1. 1.Department of GastrologyThe First Affiliated Hospital of Wenzhou Medical UniversityWenzhouChina

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