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Journal of Cluster Science

, Volume 29, Issue 6, pp 1177–1183 | Cite as

Synthesis, Structure and Photoluminescence Performance of a New Er3+-Cluster-Based 2D Coordination Polymer

  • Ugur Erkarslan
  • Adem Donmez
  • Hulya Kara
  • Muhittin Aygun
  • Mustafa Burak Coban
Original Paper
  • 66 Downloads

Abstract

A new Er3+-cluster-based 2D coordination polymer with the formula {[Er(SSA)·(H2O)2]·(H2O)}n (SSA = 5-sulfosalicylic acid), complex 1, has been successfully synthesized via hydrothermal method and structurally characterized by elemental analysis, FT-IR, UV, single crystal and powder X-ray diffraction. Complex 1 reveals the Erbium atom is coordinated to eight oxygen atoms by four symmetry-related SSA ligands and two coordinated water molecules to form a distorted square-antiprismatic geometry. The photoluminescence spectrum of the complex 1 display intense pink emission with CIE chromaticity coordinates (0.540, 0.250). The complex 1 emit NIR luminescence at 1535 nm, which corresponds to the 4I13/24I15/2 transition of Er3+ ion. Moreover, its full width at half maximum values is 113 nm. This complex can potentially be applied to polymeric erbium-doped optical amplifiers, planar waveguides or infrared OLEDs.

Keywords

Er(III) cluster Structure NIR luminescence 

Notes

Acknowledgements

The authors are grateful to the Research Funds of Mugla Sitki Kocman University (BAP-2016/52) for the financial support, Dokuz Eylul University for the use of the Agilent Xcalibur Eos diffractometer (purchased under University Research Grant No. 2010.KB.FEN.13) and Balikesir University, Science and Technology Application and Research Center (BUBTAM) for the use of the Photoluminescence Spectrometer.

Supplementary material

10876_2018_1434_MOESM1_ESM.docx (376 kb)
Supplementary material 1 (DOCX 375 kb)

References

  1. 1.
    P. Martín-Ramos, M. D. Miranda, M. R. Silva, M. E. S. Eusebio, V. Lavín, and J. Martín-Gil (2013). Polyhedron. 65, 187.CrossRefGoogle Scholar
  2. 2.
    H.-Y. Shen, W.-M. Wang, H.-L. Gao, and J.-Z. Cui (2016). RSC Adv. 6, 34165.CrossRefGoogle Scholar
  3. 3.
    X. Li, Y. Lu, Y. Bing, and M. Q. Zha (2012). Synth. React. Inorg. Met. Nano-Met. Chem. 42, 698.CrossRefGoogle Scholar
  4. 4.
    S. Alghool, M. S. Zoromba, and H. F. A. El-Halim (2013). J. Rare Earths. 31, 715.CrossRefGoogle Scholar
  5. 5.
    R. S. Zhou, L. Ye, H. Ding, J. F. Song, X. Y. Xu, and J. Q. Xu (2008). J. Solid State Chem. 181, 567.CrossRefGoogle Scholar
  6. 6.
    B. Ay, E. Yildiz, and İ. Kani (2018). Polyhedron. 142, 1.CrossRefGoogle Scholar
  7. 7.
    Z. Hnatejko, A. Kłonkowski, S. Lis, K. Czarnobaj, M. Pietraszkiewicz, and M. Elbanowski (2000). Mol. Cryst. Liq. Cryst. Sci. Technol. Sect. A Mol. Cryst. Liq. Cryst. 354, 207.CrossRefGoogle Scholar
  8. 8.
    M. Kawa and J. M. J. Fréchet (1998). Chem. Mater. 10, 286.CrossRefGoogle Scholar
  9. 9.
    C. Piguet, A. F. Williams, J. C. G. Bünzli, G. Bernardinelli, and G. Hopfgartner (1993). J. Am. Chem. Soc. 115, 8197.CrossRefGoogle Scholar
  10. 10.
    S. I. Klink, H. Keizer, and F. C. J. M. van Veggel (2000). Angew. Chemie. 39, 4319.CrossRefGoogle Scholar
  11. 11.
    Z. Lu, L. Wen, J. Yao, H. Zhu, and Q. Meng (2006). CrystEngComm. 8, 847.CrossRefGoogle Scholar
  12. 12.
    Z. Ahmed, R. E. Aderne, J. Kai, J. A. L. C. Resende, H. I. Padilla-Chavarría, and M. Cremona (2017). RSC Adv. 7, 18239.CrossRefGoogle Scholar
  13. 13.
    A. Mech, A. Monguzzi, F. Meinardi, J. Mezyk, G. Macchi, and R. Tubino (2010). J. Am. Chem. Soc. 132, 4574.CrossRefPubMedGoogle Scholar
  14. 14.
    S. Penna, A. Reale, R. Pizzoferrato, G. M. Tosi Beleffi, D. Musella, and W. P. Gillin (2007). Appl. Phys. Lett. 91, 021106.CrossRefGoogle Scholar
  15. 15.
    A. Polman (1997). J. Appl. Phys. 82, 1.CrossRefGoogle Scholar
  16. 16.
    M. B. Coban (2018). J. Mol. Struct. 1162, 109.CrossRefGoogle Scholar
  17. 17.
    M. B. Coban, C. Kocak, H. Kara, M. Aygun, and A. Amjad (2017). Mol. Cryst. Liq. Cryst. 648, 202.CrossRefGoogle Scholar
  18. 18.
    G. Oylumluoglu (2018). J. Clust. Sci. 29, 649.CrossRefGoogle Scholar
  19. 19.
    G. Oylumluoglu, M. B. Coban, C. Kocak, M. Aygun, and H. Kara (2017). J. Mol. Struct. 1146, 356.CrossRefGoogle Scholar
  20. 20.
    M. B. Coban, A. Amjad, M. Aygun, and H. Kara (2017). Inorg. Chim. Acta. 455, 25.CrossRefGoogle Scholar
  21. 21.
    J. P. Leonard and T. Gunnlaugsson (2005). J. Fluoresc. 15, 585.CrossRefPubMedGoogle Scholar
  22. 22.
    X. Zhou, X. Zhao, Y. Wang, B. Wu, J. Shen, L. Li, and Q. Li (2014). Inorg. Chem. 53, 12275.CrossRefPubMedGoogle Scholar
  23. 23.
    M. B. Coban (2017). J. Balıkesir Inst. Sci. Technol. 19, 7.Google Scholar
  24. 24.
    G. M. Sheldrick (2008). Acta Crystallogr. Sect. A Found. Crystallogr. 64, 112.CrossRefGoogle Scholar
  25. 25.
    G. M. Sheldrick (2015). Acta Crystallogr. Sect. C Struct. Chem. 71, 3.CrossRefGoogle Scholar
  26. 26.
    O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann (2009). J. Appl. Crystallogr. 42, 339.CrossRefGoogle Scholar
  27. 27.
    A. L. Spek (2009). Acta Crystallogr. Sect. D Biol. Crystallogr. 65, 148.CrossRefGoogle Scholar
  28. 28.
    X. Q. Wang, M. X. Li, X. He, M. Shao, and Z. X. Wang (2015). Inorg. Chim. Acta. 427, 273.CrossRefGoogle Scholar
  29. 29.
    M. B. Coban, U. Erkarslan, G. Oylumluoglu, M. Aygun, and H. Kara (2016). Inorg. Chim. Acta. 447, 87.CrossRefGoogle Scholar
  30. 30.
    S. Destri, M. Pasini, W. Porzio, F. Rizzo, G. Dellepiane, M. Ottonelli, G. Musso, F. Meinardi, and L. Veltri (2007). J. Lumin. 127, 601.CrossRefGoogle Scholar
  31. 31.
    N. Chen, M. X. Li, P. Yang, X. He, M. Shao, and S. R. Zhu (2013). Cryst. Growth Des. 13, 2650.CrossRefGoogle Scholar
  32. 32.
    Q. Zhong, H. Wang, G. Qian, Z. Wang, J. Zhang, J. Qiu, and M. Wang (2006). Inorg. Chem. 45, 4537.CrossRefPubMedGoogle Scholar
  33. 33.
    P. Martín-Ramos, P. S. P. Silva, P. Chamorro-Posada, M. R. Silva, B. F. Milne, F. Nogueira, and J. Martín-Gil (2015). J. Lumin. 162, 41.CrossRefGoogle Scholar
  34. 34.
    E. Gungor, M. B. Coban, H. Kara, and Y. Acar (2018). J. Clust. Sci. 2, 38.Google Scholar
  35. 35.
    M. B. Coban, E. Gungor, H. Kara, U. Baisch, and Y. Acar (2018). J. Mol. Struct. 1154, 579.CrossRefGoogle Scholar
  36. 36.
    E. Gungor, M. B. Coban, H. Kara, and Y. Acar (2018). J. Clust. Sci. 29, 533.CrossRefGoogle Scholar
  37. 37.
    S. Yoopensuk, P. Tongying, K. Hansongnern, C. Pakawatchai, S. Saithong, Y. Tantirungrotechai, and N. Leesakul (2012). Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 86, 538.CrossRefGoogle Scholar
  38. 38.
    E. Otgonbaatar, M.-C. Chung, K. Umakoshi, and C.-H. Kwak (2015). J. Nanosci. Nanotechnol. 15, 1389.CrossRefPubMedGoogle Scholar
  39. 39.
    S. Chooset, A. Kantacha, K. Chainok, and S. Wongnawa (2018). Inorg. Chim. Acta. 471, 493.CrossRefGoogle Scholar
  40. 40.
    X. Sun, B. Li, L. Song, J. Gong, and L. Zhang (2010). J. Lumin. 130, 1343.CrossRefGoogle Scholar
  41. 41.
    P. Martín-Ramos, P. Chamorro-Posada, M. Ramos Silva, P. S. Pereira Da Silva, I. R. Martín, F. Lahoz, V. Lavín, and J. Martín-Gil (2015). Opt. Mater. (Amst). 41, 139.CrossRefGoogle Scholar
  42. 42.
    Q. Sun, P. Yan, W. Niu, W. Chu, X. Yao, G. An, and G. Li (2015). RSC Adv. 5, 65856.CrossRefGoogle Scholar
  43. 43.
    S. Sarkar, V. N. K. B. Adusumalli, and V. Mahalingam (2015). Capobianco JA 17, 17577.Google Scholar
  44. 44.
    H. Wang, G. Qian, Z. Wang, J. Zhang, Y. Luo, and M. Wang (2005). J. Lumin. 113, 214.CrossRefGoogle Scholar
  45. 45.
    D. Liu, C. Li, Y. Xu, D. Zhou, H. Wang, P. Sun, and H. Jiang (2017). Polym. (U. K.) 113, 274.Google Scholar
  46. 46.
    H. Reiss and A. Heller (1985). J. Phys. Chem. 89, 4207.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Molecular Nano-Materials Laboratory, Department of Physics, Faculty of ScienceMugla Sitki Kocman UniversityMuglaTurkey
  2. 2.Scientific Research Projects Coordination UnitMugla Sitki Kocman UniversityMuglaTurkey
  3. 3.Department of Physics, Faculty of Science and ArtBalikesir UniversityBalikesirTurkey
  4. 4.Department of Physics, Faculty of Science and ArtDokuz Eylul UniversityIzmirTurkey
  5. 5.Center of Science and Technology Application and ResearchBalikesir UniversityBalikesirTurkey

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