Journal of Cluster Science

, Volume 28, Issue 6, pp 3103–3114 | Cite as

Synthesis, Structure and Magnetism of Coordination Polymers Based on [{Re4Te4(CN)12]4− Cluster Anions and [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+ (Ln = Dy, Ho, Er) Dimeric Fragments

  • Yulia M. Litvinova
  • Yakov M. Gayfulin
  • Artem S. Bogomyakov
  • Denis G. Samsonenko
  • Yuri V. Mironov
Original Paper
First Online:
Received:

Abstract

Three new polymeric compounds of general formula {[Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2][Re4Te4(CN)12]}·H2O (Ln = Dy, Ho, Er) were obtained by self-assembly reaction of [Re4Te4(CN)12]4– cluster anions, Ln3+ cations and 1,10-phenthroline (phen) in a solvothermal conditions. Single-crystal X-Ray diffraction showed that structure of compounds consist of non-charged ladder-type chains formed by [Re4Te4(CN)12]4− cluster anions and dimeric cationic complexes [Ln(phen)(H2O)3Ln(phen)(H2O)2(μ-OH)2]4+. Chains are packed parallel and linked with each other by a system of hydrogen bonds. The magnetic susceptibility of compounds is determined by exchange coupled Ln3+ ions in dimeric cationic fragments. The anisotropy effects take place and cause non-linear field dependencies of magnetization for the complexes.

Keywords

Rhenium cluster Lanthanides Coordination polymer Crystal structure Magnetic properties 
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Notes

Acknowledgement

This work was supported by the Russian Science Foundation (Project No. 14-23-00013).

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Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • Yulia M. Litvinova
    • 1
  • Yakov M. Gayfulin
    • 1
  • Artem S. Bogomyakov
    • 2
    • 3
  • Denis G. Samsonenko
    • 1
    • 2
  • Yuri V. Mironov
    • 1
    • 2
  1. 1.Nikolaev Institute of Inorganic ChemistrySB RASNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.International Tomography CenterSB RASNovosibirskRussia

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