Journal of Cluster Science

, Volume 27, Issue 5, pp 1645–1653 | Cite as

Solvothermal Synthesis, Structure and Magnetic Properties of a Novel Heterometallic Cluster with 2-Ethoxy-6-methyliminomethyl-phenol

  • Qian Jun Deng
  • Ru Xia Zhao
  • Jiming Wang
  • Chen Min Ge
  • Shu Hua Zhang
Original Paper
First Online:
Received:
  • 194 Downloads

Abstract

The reaction of Co(ClO4)2·6H2O with 3-ethoxy-2-hydrogxy-benzaldehyde, methyamine and KOH in DMF solution, under solvothermal conditions, leads to the formation of the heterotetrametallic cluster {[Co3K(emimp)4(DCA)2]·ClO4}6·(H2O) (1) (Hemimp = 2-ethoxy-6- methyliminomethyl-phenol, HDCA = Dimethyl-carbamic acid). Compound 1 displays dominant anti-ferromagnetic interactions through μ 1,1,3,3-DCA and μ 2-O bridging mode. HDCA was synthesized by in situ reaction and DMF was oxidized.

Keywords

Heterotetranuclear cluster Solvothermal synthesis Magnetic properties 
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Notes

Acknowledgments

This work was supported by the National Nature Science Foundation of China (No. 21161006), Guangdong Province Breakthrough Program in Key Areas between Guangdong and Hong Kong [No. 2012BZ100054]; The Science and Technique Innovation Foundation of Foshan City [grant number 2014HK100204]; Major Scientific Research Programs of Foshan University; the Nature Science Foundation of Guangxi Province of China (No. 2015GXNSFAA139031); Program for the scientific research and technology development plan of Guilin (No. 20150133-5) and Program of the first session backbone teacher of Guangxi of China.

Supplementary material

10876_2016_1030_MOESM1_ESM.doc (17.1 mb)
Supplementary material 1 (DOC 17523 kb)

References

  1. 1.
    E. A. Suturina, D. Maganas, E. Bill, M. Atanasov, and F. Neese (2015). Inorg. Chem. 54, (20), 9948.CrossRefGoogle Scholar
  2. 2.
    S. H. Zhang, Q. P. Huang, H. Y. Zhang, G. Li, Z. Liu, Y. Li, and H. Liang (2014). J. Coord. Chem. 67, (19), 3155.CrossRefGoogle Scholar
  3. 3.
    F. Pointillart, B. L. Guennic, O. Cador, O. Maury, and L. Ouahab (2015). Acc. Chem. Res. 48, (11), 2834.CrossRefGoogle Scholar
  4. 4.
    A. Vinslava, A. J. Tasiopoulos, W. Wernsdorfer, K. A. Abboud, and G. Christou (2016). Inorg. Chem. doi: 10.1021/acs.inorgchem.5b02790.Google Scholar
  5. 5.
    S. H. Zhang, M. H. Zeng, and H. Liang (2008). Chin. J. Sruct. Chem. 27, 785.Google Scholar
  6. 6.
    S.-H. Zhang, M. F. Tang, and C. M. Ge (2009). Z. Anorg. Allg. Chem. 635, 1442.CrossRefGoogle Scholar
  7. 7.
    C.-M. Ge, S. H. Zhang, C. Feng, Y. G. Wang, and W. Li (2011). Z. Anorg. Allg. Chem. 637, 112.CrossRefGoogle Scholar
  8. 8.
    S. H. Zhang, G. Li, H. Y. Zhang, and H. P. Li (2015). Z. Kristallogr. 230, 479.Google Scholar
  9. 9.
    Q. P. Huang, G. Li, H. Y. Zhang, S.-H. Zhang, and H. P. Li (2014). Z. Anorg. Allg. Chem. 640, 1403.CrossRefGoogle Scholar
  10. 10.
    L. Yang, Q. P. Huang, C. L. Zhang, R. X. Zhao, and S. H. Zhang (2014). Supramol. Chem. 26, 81.CrossRefGoogle Scholar
  11. 11.
    Q. P. Huang, S. H. Zhang, H. Y. Zhang, G. Li, and M. C. Wu (2014). J. Cluster Sci. 25, 1489.CrossRefGoogle Scholar
  12. 12.
    S. H. Zhang, R. X. Zhao, G. Li, H. Y. Zhang, C. L. Zhang, and G. Muller (2014). RSC Adv. 4, 54837.CrossRefGoogle Scholar
  13. 13.
    S. H. Zhang, N. Li, C. M. Ge, C. Feng, and L. F. Ma (2011). Dalton Trans. 40, 3000.CrossRefGoogle Scholar
  14. 14.
    H. Li, Z.-J. Yao, D. Liu, and G.-X. Jin (2015). Coord. Chem. Rev. 293–294, 139.CrossRefGoogle Scholar
  15. 15.
    K. Liu, W. Shi, and P. Cheng (2015). Coord. Chem. Rev. 289–290, 74.CrossRefGoogle Scholar
  16. 16.
    Bruker (2001). SMART (Version 5.0) and SAINT (Version 6.45). Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
  17. 17.
    G. M. Sheldrick (2008). Acta Cryst. A64, 112.CrossRefGoogle Scholar
  18. 18.
    G. M. Sheldrick SADABS (University of Göttingen, Göttingen, 1996).Google Scholar
  19. 19.
    S. G. Baca, T. Mikosch, M. Speldrich, J. van Leusen, A. Ellem, and P. Kogerler (2013). Inorg. Chem. 52, 4154.CrossRefGoogle Scholar
  20. 20.
    C. E. Anson, W. Klopper, J. S. Li, L. Ponikiewski, and A. Rothenberger (2006). Chem. Eur. J. 12, 2032.CrossRefGoogle Scholar
  21. 21.
    S. H. Zhang, Y. M. Jiang, Y. Xiao, and Z. Y. Zhou (2003). Chin. J. Inorg. Chem. 19, 517.Google Scholar
  22. 22.
    H. H. Zou, S. H. Zhang, Y. Xiao, C. Feng, and Y. G. Wang (2011). Struct. Chem. 22, 135.CrossRefGoogle Scholar
  23. 23.
    M. J. Hossain, M. Yamasaki, M. Mikuriya, A. Kuribayashi, and H. Sakiyama (2002). Inorg. Chem. 41, 4058.CrossRefGoogle Scholar
  24. 24.
    G. Li, W. Wang, S. H. Zhang, H. Y. Zhang, and F. Y. Chen (2014). J. Cluster Sci. 25, (6), 1589.CrossRefGoogle Scholar
  25. 25.
    Y. Xu, Y. X. Che, and J. M. Zheng (2013). Z. Anorg. Allg. Chem. 639, 784.CrossRefGoogle Scholar
  26. 26.
    L. Zhang, W. Li, J. Zhang, Z. J. Li, Y. Y. Qin, J. K. Cheng, and Y. G. Yao (2008). Inorg. Chem. Commun. 11, 279.CrossRefGoogle Scholar
  27. 27.
    J. G. Wang, N. Chai, S. C. Wang, L. F. Ma, and L. Y. Wang (2013). Inorg. Chem. Commun. 30, 143.CrossRefGoogle Scholar
  28. 28.
    S. Konar, E. Zangrando, M. G. B. Drew, J. Ribas, and N. R. Chaudhuri (2004). Dalton Trans. 33, 260.CrossRefGoogle Scholar
  29. 29.
    S. H. Zhang, Y. Song, H. Liang, and M. H. Zeng (2009). CrystEngComm 11, 865.CrossRefGoogle Scholar
  30. 30.
    S. H. Zhang, Y. M. Jiang, and Z.-M. Liu (2008). J. Coord. Chem. 61, 1927.CrossRefGoogle Scholar
  31. 31.
    S. H. Zhang, G. Li, H. Y. Zhang, and H. P. Li (2015). Z. Kristallogr. 2015, (230), 479.Google Scholar
  32. 32.
    M. Shebl (2014). Spectrochim. Acta A 117, 127.CrossRefGoogle Scholar
  33. 33.
    S. H. Zhang, R. X. Zhao, G. Li, H. Y. Zhang, Q. P. Huang, and F. P. Liang (2014). J. Solid State Chem. 220, 206.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Qian Jun Deng
    • 1
    • 2
  • Ru Xia Zhao
    • 2
  • Jiming Wang
    • 2
  • Chen Min Ge
    • 2
  • Shu Hua Zhang
    • 2
  1. 1.School of Material Science and Energy EngineeringFoshan UniversityFoshanPeople’s Republic of China
  2. 2.College of Chemistry and Bioengineering, (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi)Guilin University of TechnologyGuilinPeople’s Republic of China

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