Journal of Cluster Science

, Volume 26, Issue 5, pp 1567–1576 | Cite as

Protonated 2-Aminonicotinic Acid as Charge Complement in POM-Based Inorganic–Organic Hybrids: Synthesis, Crystal Structure and Characterization

  • Dong-Xiao Wang
  • Hong-Bo Liu
  • Ya-Guang Chen
  • Shan Wei
Original Paper
First Online:
Received:
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Abstract

Two supramolecular compounds, (2-HANA)4(SiW12O40)·12H2O (1) and (H3O)(2-HANA)2(HPW12O40)·11H2O (2), ANA = 2-aminonicotinic acid, were synthesized in conventional method in aqueous solution and characterized with elemental analysis, IR spectrography, thermal analysis. Their crystal structures were determined with X-ray single-crystal diffraction and CV behavior were examined. In the compounds ANA is protonated and acts as charge complement and hydrogen bond donor and acceptor. In 1 there is a supramolecular chain formed through fourfold hydrogen bonds between water molecules and SiW12 anions, and in 2 a supramolecular layer is formed by hydrogen bonds between protonated O1W molecules and PW12 anions. The protonated water molecule is identified from IR spectrum of 2.

Keywords

2-Aminonicotinic acid Keggin anion Supramolecular compound Crystal structure 
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Supplementary material

10876_2015_851_MOESM1_ESM.docx (942 kb)
Supplementary material 1 (DOCX 941 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Dong-Xiao Wang
    • 1
  • Hong-Bo Liu
    • 2
  • Ya-Guang Chen
    • 1
  • Shan Wei
    • 1
  1. 1.Key Laboratory of Polyoxometalates Science of Ministry of Education, College of ChemistryNortheast Normal UniversityChangchunPeople’s Republic of China
  2. 2.Department of PharmaceuticsChangchun Medical CollegeChangchunPeople’s Republic of China

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