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Journal of Cluster Science

, Volume 24, Issue 3, pp 935–944 | Cite as

Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Based on Glutaric Acid and Triazole

  • Guang-Xiang LiuEmail author
Brief Communication
  • 161 Downloads

Abstract

A new coordination polymer, [Cd7(μ 3-O)2(glut)2(Hglut)2(trz)4]n (1) (H2glut = glutaric acid and Htrz = 1,2,4-triazole), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a fairly complicated three-dimensional (3D) (3,3,6,10)-connected framework constructed from two-dimensional (2D) infinite [Cd7(μ 3-O)2(glut)4(Hglut)2]n layers and [Cd(trz)4]2− units. Moreover, the thermal stability and photoluminescent properties of 1 were also investigated.

Keywords

Cadmium(II) coordination polymer Glutaric acid 1,2,4-triazole Crystal structure Luminescence 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21271106), the Key Project of Chinese Ministry of Education (No. 210102) and Qing Lan Project of Jiangsu Provincial Department of Education.

Supplementary material

10876_2013_574_MOESM1_ESM.docx (25 kb)
(DOCX 25 kb)

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.School of Biochemical and Environmental EngineeringNanjing Xiaozhuang UniversityNanjingPeople’s Republic of China

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