Journal of Cluster Science

, Volume 20, Issue 2, pp 453–465 | Cite as

The 20-Tungsto-4-Tellurate(IV) [H2Te4W20O80]22− and the 15-Tungstotellurate(IV) [NaTeW15O54]13−

  • Amal H. Ismail
  • Nadeen H. Nsouli
  • Michael H. Dickman
  • Jakša Knez
  • Ulrich Kortz
Original Paper

Abstract

The 20-tungsto-4-tellurate(IV) polyanion [H2Te4W20O80]22− (1) has been synthesized and isolated in the form of its hydrated sodium salt Na22[H2Te4W20O80]·64H2O (Na-1). Na-1 has been characterized in the solid state by FTIR and TGA. Single-crystal X-ray diffraction analysis revealed that Na-1 crystallizes in the triclinic space group P\({\bar 1}\), with = 12.741(2) Å, b = 16.842(3) Å, c = 17.197(4) Å, α = 93.961(10)°, β = 107.466(8)°, γ = 108.548(8)°, V = 3281.5(11) Å3 and Z = 1. The polyanion 1 comprises two [HTe2W10O40]11− fragments, connected through Te−O–W μ2-oxo bridges, and each containing a pair of face-shared WO6 octahedra. Furthermore, the 15-tungstotellurate(IV) polyanion [NaTeW15O54]13− (2) was synthesized and crystallized as a sodium salt in the orthorhombic space group Pccn, with = 11.8841(5) Å, b = 20.8934(11) Å, c = 31.801(2) Å, V = 7896.3(7) Å3 and Z = 4.

Keywords

Polyoxometalates Tungsten Tellurium X-ray crystal structure Face-shared octahedra 

Supplementary material

10876_2009_245_MOESM1_ESM.doc (92 kb)
Supplementary material 1 (DOC 92 kb)

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Amal H. Ismail
    • 1
  • Nadeen H. Nsouli
    • 1
  • Michael H. Dickman
    • 1
  • Jakša Knez
    • 1
  • Ulrich Kortz
    • 1
  1. 1.School of Engineering and ScienceJacobs UniversityBremenGermany

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