Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7-phosphaadamantane)

Original Paper
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Abstract

Zn(II) and Cu(II) complexes of the cluster-based ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7-phosphaadamantane), {Zn[Re6(μ 3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (1) and {Cu[Re6(μ 3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

Keywords

Rhenium chalcogenide clusters Water-soluble ligand Coordination Crystal structure 
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Notes

Acknowledgements

This research was supported in part by the National Science Foundation (CHE-0750530). The X-ray diffractometer was purchased through an NSF grant (CHE-96103474). We thank Xiangjian Kong, Xia’men University, for crystallographic data collection of 2.

Supplementary material

10876_2008_206_MOESM1_ESM.doc (143 kb)
(DOCX 143 kb).

References

  1. 1.
    Y. V. Mironov, N. G. Naumov, K. A. Brylev, O. A. Efremova, V. E. Fedorov, and K. Hegetschweiler (2004). Angew. Chem. Int. Ed. 43, 1297.CrossRefGoogle Scholar
  2. 2.
    N. G. Naumov, A. V. Virovets, M. N. Sokolov, S. B. Artemkina, and V. E. Fedorov (1998). Angew. Chem. Int. Ed. 37, 1943.CrossRefGoogle Scholar
  3. 3.
    M. A. Shestopalov, Y. V. Mironov, K. A. Brylev, S. G. Kozlova, V. E. Fedorov, H. Spies, H.-J. Pietzsch, H. Stephan, G. Geipel, and G. Bernhard (2007). J. Am. Chem. Soc. 129, 3714.CrossRefGoogle Scholar
  4. 4.
    L. F. Szczepura, M. K. Oh, and S. A. Knott (2007). Chem. Commun. 44, 4617.CrossRefGoogle Scholar
  5. 5.
    J. C. Gabriel, K. Boubekeur, S. Uriel, and P. Batail (2001). Chem. Rev. 101, 2037.CrossRefGoogle Scholar
  6. 6.
    J. R. Long, L. S. McCarty, and R. H. Holm (1996). J. Am. Chem. Soc. 118, 4603.CrossRefGoogle Scholar
  7. 7.
    M. V. Bennett, L. G. Beauvais, M. P. Shores, and J. R. Long (2001). J. Am. Chem. Soc. 123, 8022.CrossRefGoogle Scholar
  8. 8.
    G. L. Beauvais, P. S. Matthew, and J. R. Long (2000). J. Am. Chem. Soc. 122, 2763.CrossRefGoogle Scholar
  9. 9.
    Y. Sasaki (2005). J. Nucl. Radiochem. Sci. 6, 145.Google Scholar
  10. 10.
    H. D. Selby, B. K. Roland, and Z. Zheng (2003). Acc. Chem. Res. 36, 933.CrossRefGoogle Scholar
  11. 11.
    H. D. Selby, B. K. Roland, J. R. Cole, and Z. Zheng (2004). Macromol. Symp. 209, 23.CrossRefGoogle Scholar
  12. 12.
    G. Pilet and A. Perrin (2005). C. R. Chimie. 8, 1728.Google Scholar
  13. 13.
    A. Deluzet, H. Duclusaud, P. Sautet, and S. A. Borshch (2002). Inorg. Chem. 41, 2537.CrossRefGoogle Scholar
  14. 14.
    S. A. Baudron, A. Deluzet, K. Boubekeur, and P. Batail (2002). Chem. Commun. 18, 2124.CrossRefGoogle Scholar
  15. 15.
    P. J. Orto, G. S. Nichol, N. Okumura, D. H. Evans, R. Arratia-Perez, R. Ramirez-Tagle, R. Wang, and Z. Zheng (2008). Dalton Trans. 32, 4247.CrossRefGoogle Scholar
  16. 16.
    R. Brusetti, O. Laborde, A. Sulpice, R. Calemczuk, M. Potel, and P. Gougeon (1995). Phys. Rev. B Condens. Matter. 52, 4481.Google Scholar
  17. 17.
    S. Belin, R. Chevrel, and M. Sergent (1999). J. Solid State Chem. 145, 159.CrossRefGoogle Scholar
  18. 18.
    M. D. Levi and D. Aurbach (2005). J. Power Sourc. 146, 349.CrossRefGoogle Scholar
  19. 19.
    J. Neuhausen, E. W. Finckh, and W. Tremel (1996). Inorg. Chem. 35, 5622.CrossRefGoogle Scholar
  20. 20.
    K. Tsuge, H. Imoto, and T. Saito (1996). Bull. Chem. Soc. Jpn. 69, 627.CrossRefGoogle Scholar
  21. 21.
    L. Leduc, A. Perrin, M. Sergent, F. Le Traon, J. C. Pilet, and A. Le Traon (1985). Mater. Lett. 3, 209.CrossRefGoogle Scholar
  22. 22.
    V. E. Fedorov, A. V. Mishchenko, B. A. Kolesov, S. P. Gubin, Y. L. Slovokhotov, and Y. T. Struchkov (1985). Koord. Khim. 11, 1701.Google Scholar
  23. 23.
    J. S. Long, A. S. Williamson, and R. H. Holm (1995). Angew. Chem. Int. Ed. Engl. 34, 226.CrossRefGoogle Scholar
  24. 24.
    Z. Zheng, J. R. Long, and R. H. Holm (1997). J. Am. Chem. Soc. 119, 2163.CrossRefGoogle Scholar
  25. 25.
    Z. Zheng, T. G. Gray, and R. H. Holm (1999). Inorg. Chem. 38, 4888.CrossRefGoogle Scholar
  26. 26.
    T. G. Gray and R. H. Holm (2002). Inorg. Chem. 41, 4211.CrossRefGoogle Scholar
  27. 27.
    R. Arratia-Perez and L. Hernandez-Acevedo (1999). J. Chem. Phys. 111, 168.CrossRefGoogle Scholar
  28. 28.
    R. Arratia-Perez and L. Hernandez-Acevedo (1999). J. Chem. Phys. 110, 2529.CrossRefGoogle Scholar
  29. 29.
    T. G. Gray, C. M. Rudzinski, D. G. Nocera, and R. H. Holm (1999). Inorg. Chem. 38, 5932.CrossRefGoogle Scholar
  30. 30.
    T. G. Gray, C. M. Rudzinski, E. E. Meyer, R. H. Holm, and D. G. Nocera (2003). J. Am. Chem. Soc. 125, 4755.CrossRefGoogle Scholar
  31. 31.
    Z.-N. Chen, T. Yoshimura, M. Abe, Y. Sasaki, S. Ishizaka, H.-B. Kim, and N. Kitamura (2001). Angew. Chem. Int. Ed. 40, 239.CrossRefGoogle Scholar
  32. 32.
    T. Yoshimura, Z.-N. Chen, A. Itasaka, M. Abe, Y. Sasaki, S. Ishizaka, N. Kitamura, S. S. Yarovoi, S. F. Solodovnikov, and V. E. Fedorov (2003). Inorg. Chem. 42, 4857.CrossRefGoogle Scholar
  33. 33.
    B. K. Roland, W. H. Flora, H. D. Selby, N. R. Armstrong, and Z. Zheng (2006). J. Am. Chem. Soc. 128, 6620.CrossRefGoogle Scholar
  34. 34.
    Z. Zheng and R. H. Holm (1997). Inorg. Chem. 36, 5173.CrossRefGoogle Scholar
  35. 35.
    R. Wang and Z. Zheng (1999). J. Am. Chem. Soc. 121, 3549.CrossRefGoogle Scholar
  36. 36.
    B. K. Roland, H. D. Selby, M. D. Carducci, and Z. Zheng (2002). J. Am. Chem. Soc. 124, 3222.CrossRefGoogle Scholar
  37. 37.
    P. Orto, H. D. Selby, D. Ferris, J. R. Maeyer, and Z. Zheng (2007). Inorg. Chem. 46, 4377.CrossRefGoogle Scholar
  38. 38.
    K. A. Brylev, G. Pilet, N. G. Naumov, A. Perrin, and V. E. Fedorov (2005). Eur. J. Inorg. Chem. 461.Google Scholar
  39. 39.
    S. S. Yarovoi, Y. V. Mironov, D. Y. Naumov, Y. V. Gatilov, S. G. Kozlova, S-J. Kim, and V. E. Fedorov (2005). Eur. J. Inorg. Chem. 3945.Google Scholar
  40. 40.
    K. A. Brylev, Y. V. Mironov, S. S. Yarovoi, N. G. Naumov, V. E. Fedorov, S.-J. Kim, N. Kitamura, Y. Kuwahara, K. Yamada, S. Ishizaka, and Y. Sasaki (2007). Inorg. Chem. 46, 7414.CrossRefGoogle Scholar
  41. 41.
    A. Itasaka, M. Abe, T. Yoshimura, K. Tsuge, M. Suzuki, T. Imamura, and Y. Sasaki (2002). Angew. Chem. Int. Ed. 41, 463.CrossRefGoogle Scholar
  42. 42.
    T. Yoshimura, K. Umakoshi, Y. Sasaki, S. Ishizaka, H.-B. Kim, and N. Kitamura (2000). Inorg. Chem. 39, 1765.CrossRefGoogle Scholar
  43. 43.
    M. P. Shores, L. G. Beauvais, and J. R. Long (1999). J. Am. Chem. Soc. 121, 775.CrossRefGoogle Scholar
  44. 44.
    L. G. Beauvais, M. P. Shores, and J. R. Long (1998). Chem. Mater. 10, 3783.CrossRefGoogle Scholar
  45. 45.
    H. D. Selby, Z. Zheng, T. G. Gray, and R. H. Holm (2001). Inorg. Chim. Acta. 312, 205.CrossRefGoogle Scholar
  46. 46.
    B. K. Roland, W. H. Flora, N. R. Armstrong, and Z. Zheng (2005). C. R. Chim. 8, 1798.Google Scholar
  47. 47.
    B. K. Roland, H. D. Selby, J. R. Cole, and Z. Zheng (2003). Dalton Trans. 4307.Google Scholar
  48. 48.
    H. D. Selby, B. K. Roland, M. D. Carducci, and Z. Zheng (2003). Inorg. Chem. 42, 1656.CrossRefGoogle Scholar
  49. 49.
    H. D. Selby, P. Orto, M. D. Carducci, and Z. Zheng (2002). Inorg. Chem. 41, 6175.CrossRefGoogle Scholar
  50. 50.
    H. D. Selby, P. Orto, and Z. Zheng (2003). Polyhedron. 22, 2999.CrossRefGoogle Scholar
  51. 51.
    D. J. Daigle, A. B. Pepperman, and S. L. Vail (1974). J. Heterocycl. Chem. 1974, (11), 407–408.CrossRefGoogle Scholar
  52. 52.
    A. D. Phillips, L. Gonsalvi, A. Romerosa, F. Vizza, and M. Peruzzini (2004). Coord. Chem. Rev. 248, 955.CrossRefGoogle Scholar
  53. 53.
    X. Tang, B. Zhang, Z. He, R. Gao, and Z. He (2007). Adv. Synth. Catal. 349, 2007.CrossRefGoogle Scholar
  54. 54.
    J. Ruiz, N. Cutillas, F. Lopez, G. Lopez, and D. Bautista (2006). Organometallics. 25, 5768.CrossRefGoogle Scholar
  55. 55.
    F. Mohr, L. R. Falvello, and M. Laguna (2006). Eur. J. Inorg. Chem. 3152.Google Scholar
  56. 56.
    S. S. Bosquain, A. Dorcier, P. J. Dyson, M. Erlandsson, L. Gonsalvi, G. Laurenczy, and M. Peruzzini (2007). Appl. Organometal. Chem. 21, 947.CrossRefGoogle Scholar
  57. 57.
    B. Korthals, I. Goettker-Schnetmann, and S. Mecking (2007). Organometallics. 26, 1311.CrossRefGoogle Scholar
  58. 58.
    C. A. Mebi, R. P. Nair, and B. J. Frost (2007). Organometallics. 26, 429.CrossRefGoogle Scholar
  59. 59.
    F. Mohr, S. Sanz, E. R. T. Tiekink, and M. Laguna (2006). Organometallics. 25, 3084.CrossRefGoogle Scholar
  60. 60.
    D. A. Krogstad, J. Cho, A. J. DeBoer, J. A. Klitzke, W. R. Sanow, H. A. Williams, and J. A. Halfen (2006). Inorg. Chim. Acta. 359, 136.CrossRefGoogle Scholar
  61. 61.
    S. Bolano, L. Gonsalvi, F. Zanobini, F. Vizza, V. Bertolasi, A. Romerosa, and M. Peruzzini (2004). J. Mol. Catal. A Chem. 224, 61.CrossRefGoogle Scholar
  62. 62.
    P. Csabai and F. Joo (2004). Organometallics. 23, 5640.CrossRefGoogle Scholar
  63. 63.
    H. Horvath, G. Laurenczy, and A. Katho (2004). J. Organomet. Chem. 689, 1036.CrossRefGoogle Scholar
  64. 64.
    G. Kovacs, L. Nadasdi, G. Laurenczy, and F. Joo (2003). Green Chem. 5, 213.CrossRefGoogle Scholar
  65. 65.
    F. Joo, L. Nadasdi, A. Cs Benyei, and D. J. Darensbourg (1996). J. Organomet. Chem. 512, 45.CrossRefGoogle Scholar
  66. 66.
    D. J. Darensbourg, N. W. Stafford, F. Joo, and J. H. Reibenspies (1995). J. Organomet. Chem. 488, 99.CrossRefGoogle Scholar
  67. 67.
    A. M. M. Meij, S. Otto, and A. Roodt (2005). Inorg. Chim. Acta. 358, 1005.CrossRefGoogle Scholar
  68. 68.
    D. A. Krogstad, J. A. Halfen, T. J. Terry, and V. G. Young Jr (2001). Inorg. Chem. 40, 463.CrossRefGoogle Scholar
  69. 69.
    S. Grguric-Sipka, C. R. Kowol, S. Valiahdi, R. Eichinger, M. A. Jakupec, A. Roller, S. Shova, V. B. Arion, and B. K. Keppler (2007). Eur. J. Inorg. Chem. 2870.Google Scholar
  70. 70.
    P. Bergamini, V. Bertolasi, L. Marvelli, A. Canella, R. Gavioli, N. Mantovani, S. Manas, and A. Romerosa (2007). Inorg. Chem. 46, 4267.CrossRefGoogle Scholar
  71. 71.
    C. Gossens, I. Tavernelli, and U. Rothlisberger (2005). Chimia. 59, 81.CrossRefGoogle Scholar
  72. 72.
    S. Alidori, G. Gioia Lobbia, G. Papini, M. Pellei, M. Porchia, F. Refosco, F. Tisato, J. S. Lewis, and C. Santini (2008). J. Biol. Inorg. Chem. 13, 307.CrossRefGoogle Scholar
  73. 73.
    C. Scolaro, A. B. Chaplin, C. G. Hartinger, A. Bergamo, M. Cocchietto, B. K. Keppler, G. Sava, and P. J. Dyson (2007). Dalton Trans. 43, 5065.CrossRefGoogle Scholar
  74. 74.
    W. H. Ang, E. Daldini, L. Juillerat-Jeanneret, and P. J. Dyson (2007). Inorg. Chem. 46, 9048.CrossRefGoogle Scholar
  75. 75.
    L. Leyva, C. Sirlin, L. Rubio, C. Franco, R. Le Lagadec, J. Spencer, P. Bischoff, C. Gaiddon, J. Loeffler, and M. Pfeffer (2007). Eur. J. Inorg. Chem. 3055.Google Scholar
  76. 76.
    L. Jaremko, A. M. Kirillov, P. Smolenski, T. Lis, and A. J. L. Pombeiro (2008). Inorg. Chem. 47, 2922.CrossRefGoogle Scholar
  77. 77.
    S. Bolano, A. Albinati, J. Bravo, L. Gonsalvi, and M. Peruzzini (2006). Inorg. Chem. Commun. 9, 360.CrossRefGoogle Scholar
  78. 78.
    B. J. Frost, C. M. Bautista, R. Huang, and J. Shearer (2006). Inorg. Chem. 45, 3481.CrossRefGoogle Scholar
  79. 79.
    B. J. Frost, C. A. Mebi, and P. W. Gingrich (2006). Eur. J. Inorg. Chem. 1182.Google Scholar
  80. 80.
    C. Lidrissi, A. Romerosa, M. Saoud, M. Serrano-Ruiz, L. Gonsalvi, and M. Peruzzini (2005). Angew. Chem. Int. Ed. 44, 2568.CrossRefGoogle Scholar
  81. 81.
    F. Mohr, L. R. Falvello, and M. Laguna (2006). Eur. J. Inorg. Chem. 3152.Google Scholar
  82. 82.
    X. Tu, G. S. Nichol, R. Wang, and Z. Zheng (2008). Dalton Trans. (in press).Google Scholar
  83. 83.
    SMART and SAINT (Bruker AXS Inc., Madison, Wisconsin, USA, 2007).Google Scholar
  84. 84.
    SADABS and G. M. Sheldrick (University of Göttingen, Germany, 1996).Google Scholar
  85. 85.
    G. M. Sheldrick (2008). Acta Crystallogr. Sect. A. 64, 112–122.CrossRefGoogle Scholar
  86. 86.
    S. Bolano, A. Albinati, J. Bravo, M. Caporali, L. Gonsalvi, L. Male, M. Mar Rodriguez-Rocha, A. Rossin, and M. Peruzzini (2008). J. Organometall. Chem. 693, 2397.CrossRefGoogle Scholar
  87. 87.
    A. Kirillov, P. Smolenski, M. Silva, and A. Pombeiro (2007). Eur. J. Inorg. Chem. 2686.Google Scholar
  88. 88.
    F. H. Allen (2002). Acta Crystallogr. Sect. B. 58, 380.CrossRefGoogle Scholar
  89. 89.
    D. F. Shriver, and P. W. Atkins Inorganic Chemistry (Oxford University Press, 1999), Vol. 3, pp. 235–236.Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.Department of ChemistryThe University of ArizonaTucsonUSA

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