Journal of Cluster Science

, Volume 16, Issue 1, pp 65–76 | Cite as

Hydrothermal Synthesis and Structural Characterization of a Tubular Arsenic-Vanadate: [Co II (2,2′-bpy)2]2[As III 8V IV 14O42(H2O)]·H2O

  • Chun-Mei Wang
  • Qing-Xin Zeng
  • Jie Zhang
  • Guo-Yu Yang
Article
Received:

Abstract

The hydrothermal reaction of VOSO4, As2O3, CoC2O4·2H2O and 2,2′-bipy yields a novel arsenic-vanadate [CoII(2,2′-bpy)2]2[AsIII8VIV 14O42(H2O)]·H2O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic–vanadium cluster containing infinite {[Co(2,2′-bpy)2]2[As8V14O42(H2O)]}∞ chain constructed from [As8V14O42(H2O)] clusters interconnected through [Co(2,2-bpy)]2+ units. Crystal data: 1, orthorhombic, P 212121, a=12.1401(2) Å, b=15.8722(1) Å, c=39.9533(5) Å, Z=4.

Graphical Abstract: A novel polyoxoarsenicvanadate, [CoII(2,2′-bipy)2]2 [AsIII8VIV 14O42(H2O)]·H2O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain.

Key words:

Polyoxometalate vanadium arsenic cobalt crystal structure hydrothermal synthesis 
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References

  1. 1.
    Schubert, U, Voltel, T, Moszner, N 2001Mater. Chem.133811Google Scholar
  2. 2.
    Feng, S.-H., Xu, R.-R. 2001Acc. Chem. Rev.34239Google Scholar
  3. 3.
    Bourlinos, A. B., Petridis, D., Karakosdas, Th. 2003J. Phys. Chem. B.107920Google Scholar
  4. 4.
    Lin, Z.-E., Zhang, J., Sun, Y.-Q., Yang, G.-Y. 2004Inorg. Chem.43797Google Scholar
  5. 5.
    C. F. Robert, E. Burkholderand J. Zubieta (2001). Chem. Commun. 1582.Google Scholar
  6. 6.
    E. Burkholder and J. Zubieta (2001). Chem. Commun. 2056.Google Scholar
  7. 7.
    Pope, M. T. 1983Heteropoly and Isopoly OxometalatesSpringer-verlagBerlinGoogle Scholar
  8. 8.
    Pope, T. M.Müller, A. eds. 2001Polyoxometalate Chemistry: From Topology via Self-Assembly to ApplicationsKluwer Academic publishersDordrecht, NetherlandsGoogle Scholar
  9. 9.
    Kozhevniciv, I. V. 1998Chem. Rev.98171Google Scholar
  10. 10.
    Mizuno, N., Misono, M. 1998Chem. Rev.98199Google Scholar
  11. 11.
    Rhule, J. T., Hill, C. L., Judd, D. A., Schinazi, R. F. 1998Chem. Rev.98327Google Scholar
  12. 12.
    Yamase, T.Pope, T. M. eds. 2002Polyoxometalate Chemistry for Nono-Composite Design; Nonostructure Science and TechnologyKluwer Academic/Plenum PublishingNew YorkGoogle Scholar
  13. 13.
    Riou, D., Frey, G. 1995J. Solid State Chem.120137Google Scholar
  14. 14.
    Nazar, L. F., Koene, B. E., Britten, J. 1996Chem. Mater.8327Google Scholar
  15. 15.
    Y. Zhang, R. C. Haushalterand A. Clearfield (1996). Chem. Commun. 1055.Google Scholar
  16. 16.
    T. G. Chirayil, P. Y. Zavalij, and M. S. Whittingham (1997). J. Mater. Chem. 7, 2193.Google Scholar
  17. 17.
    S. D. Huang and Y. Shan (1998). Chem. Commun. 1069.Google Scholar
  18. 18.
    Law, T. S.-C., Williams, I. D. 2000Chem. Mater.122070Google Scholar
  19. 19.
    Zhang, Y., Zapf, P. J., Meyer, L. M., Haushalter, R. C., Zubieta, J. 1997Inorg. Chem.362159Google Scholar
  20. 20.
    Hagrman, D., Zapf, P. J., Zubieta, J. 1998Chem. Commun.221283Google Scholar
  21. 21.
    Wu, , Lu, C. Z., Zhang, H. H., Huang, J. S. 2002J. Am. Chem. Soc.1243836Google Scholar
  22. 22.
    Crans, D. C., Smee, J. J., Gaidamauskas, E., Yang, L. Q. 2004Chem. Rev.104849Google Scholar
  23. 23.
    Yuan, M., Li, Y.-G., Wang, E.-B., Tian, C.-G., Wang, L., Hu, C.-W., Hu, N.-H., Jia, H.-Q. 2003Inorg. Chem.423670Google Scholar
  24. 24.
    Khan, M. I., Yohannes, E., Doedens, R. J. 2003Inorg. Chem.423125Google Scholar
  25. 25.
    Müller, A., Döring, J. 1991Z. Anorg. Allg. Chem.595251reference therein.Google Scholar
  26. 26.
    (a) A. Müller and J. Döring (1988). Angew. Chem., Int. Ed. 27, 1721; (b) G.-Y. Yang, L. Chen, J.-Q. Xu, Y. Li, H. Sun, Z. Pei, Q. Su, Y. Lin, Y. Xing, H. Jia (1998). Acta Cryst. Sect. C, 54, 1556.Google Scholar
  27. 27.
    G. Huan, M.A. Greaney, and A.J. Jacobson (1991). J. Chem. Soc., Chem.Commun. 260.Google Scholar
  28. 28.
    X.-Q. Wang, L.-M. LiuG. Zhang, and A. J. Jacobson (2001). J. Chem. Soc., Chem. Commun. 2472.Google Scholar
  29. 29.
    Whitfield, T., Wang, X., Jacobson, A. J. 2003Inorg. Chem.423728Google Scholar
  30. 30.
    Tripathi, A., Hughbanks, T., Clearfield, A. 2003J. Am. Chem. Soc.12510528Google Scholar
  31. 31.
    Hu, X.-X., Xu, J.-Q., Cui, X.-B., Song, J.-F., Wang, T.-G. 2004Inorg. Chem. Commun.7264Google Scholar
  32. 32.
    Cui, X.-B., Xu, J.-Q., Li, Y., Sun, Y.-H., Ye, L., Yang, G.-Y. 2003J. Molec. Struct.657395Google Scholar
  33. 33.
    Cui, X.-B., Sun, Y.-Q., Yang, G.-Y. 2003Inorg. Chem. Commun.6259Google Scholar
  34. 34.
    Cui, X.-B., Xu, J.-Q., Sun, Y.-H., Li, Y., Ye, L., Yang, G.-Y. 2004Inorg. Chem. Commun.758Google Scholar
  35. 35.
    W.-M. Bu, G.-Y. Yang, L. Ye, J.-Q. Xu, and Y.-G. Fan (2000) Chem. Lett. 462Google Scholar
  36. 36.
    G. M. Sheldrick 1997 A program for the Siemens Area Detector ABSorption correction University of Göettingen.Google Scholar
  37. 37.
    Sheldrick, G. M. 1997SHELXS97 Program for Solution of Crystal StructuresUniversity of GöettingenGermanyGoogle Scholar
  38. 38.
    Sheldrick, G. M. 1997SHELXL97 Program for Solution of Crystal StructuresUniversity of GöettingenGermanyGoogle Scholar
  39. 39.
    Jonson, G. K., Schlemper, E. O. 1978J. Am.Chem. Soc.1003645Google Scholar
  40. 40.
    Brown, I. D., Altermatt, D. A. 1985Acta Cryst. Sect. B41244Google Scholar
  41. 41.
    Khan, M. I. 2000J. Solid State Chem.152105Google Scholar
  42. 42.
    Khan, M. I., Yohannes, E., Doedens, R. J. 1999Angew. Chem. Int. Ed.381292CrossRefGoogle Scholar
  43. 43.
    M. I. Khan, E. Yohannes, and D. Powell (1999). J. Chem. Soc., Chem. Commun. 23.Google Scholar
  44. 44.
    Khan, M. I., Yohannes, E., Powell, D. 1999Inorg. Chem.38212Google Scholar
  45. 45.
    Debord, J. R. D., Haushalter, R. C., Meyer, L. M., Rose, D. J., Zapf, P. J., Zubieta, J. 1997Inorg. Chim. Acta.256165Google Scholar
  46. 46.
    R. L. LaDuca, M. Desciak, M. LaskoskiR. S. Rarig, and J. Zubieta (2000). J. Chem. Soc., Dalton. Trans. 2255.Google Scholar
  47. 47.
    E. Burkholder, and J. Zubieta (2001) J. Chem. Soc., Chem. Commun. 2056Google Scholar
  48. 48.
    C.-M. Liu, D.-Q. Zhang, M. Xiong, and D.-B. Zhu (2002) J. Chem. Soc., Chem. Commun. 1416Google Scholar
  49. 49.
    Lei, C., Mao, J.-G., Sun, Y.-Q., Song, J.-L. 2004Inorg. Chem.431964Google Scholar
  50. 50.
    Khan, M. I., Yohannes, E., Doedens, R. J. 2003Inorg. Chem.423125Google Scholar
  51. 51.
    P. J. Zapf, C. J. Warren, R. C. Haushalter, and J. Zubieta (1997) J. Chem. Soc., Chem. Commun. 1543Google Scholar
  52. 52.
    Shivaiah, V., Nagaraju, M., Das, S. K. 2003Inorg. Chem.426604Google Scholar
  53. 53.
    Barra, A. L., Gatteschi, D., Pardi, L., Müller, A., Doring, J. 1992J. Am. Chem. Soc.1148509Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • Chun-Mei Wang
    • 1
  • Qing-Xin Zeng
    • 1
  • Jie Zhang
    • 1
  • Guo-Yu Yang
    • 1
  1. 1.State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesFuzhouChina

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