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Journal of Atmospheric Chemistry

, Volume 54, Issue 2, pp 89–102 | Cite as

A Study of the Reaction of OH Radicals with N-Methyl Pyrrolidinone,N-Methyl Succinimide and N-Formyl Pyrrolidinone

  • G. Solignac
  • I. Magneron
  • A. MelloukiEmail author
  • A. Muñoz
  • M. Martin Reviejo
  • K. Wirtz
Article

Abstract

A study of the oxidation mechanism of N-methyl pyrrolidinone (C5H9NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of cm3 molecule − 1 s− 1): kNMP = (2.2 ± 0.4) × 10− 11, kNMS = (1.4 ± 0.3) × 10− 12 and kFP = (6 ± 1) × 10− 12. The results are presented and discussed in terms of the atmospheric impact.

Keywords

N-methyl pyrrolidinone N-methyl succinimide N-formyl pyrrolidinone hydroxyl radicals relative kinetic troposphere 

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References

  1. Aschmann, M. S. and Atkinson, R., 1999: Atmospheric chemistry of 1-methyl-2-pyrrolidinone, Atmos. Environ. 33, 591–599.CrossRefGoogle Scholar
  2. Atkinson, R., 1991: Kinetics and mechanisms of the gas phase reactions of the NO3 radical with organic compounds, Phys. Chem. Ref. Data 20, 459–507.CrossRefGoogle Scholar
  3. Becker, K. H., 1996: The European Photoreactor “EUPHORE”, final report, EC contract EV5V-CT92-0059, university of Wuppertal.Google Scholar
  4. Calvert, J. G., Atkinson, R., Becker, K. H., Kamens, R. M., Seinfeld, J. H., Wallington, T. J., and Yarwood, G., 2002: Mechanism of atmospheric oxidation of aromatic hydrocarbons.Google Scholar
  5. Calvert, J. G., Atkinson, R., Kerr, J. A., Madronich, S., Moortgat, G. K., Wallington, T. J., and Yarwood, G., 2000: Mechanisms of the atmospheric oxidation of the alkenes.Google Scholar
  6. Chakir, A., Solignac, G., Mellouki, A., and Daumont, D., 2005: Gas phase UV absorption cross-sections for a series of amides, Chem. Phys. Lett. 404, 74–78.CrossRefGoogle Scholar
  7. Derwent, R. G., Jenkin, M. E., and Saunders, S. M., 1996: Photochemical ozone creation potential for a large number of reactive hydrocarbons under european conditions, Atm. Environ. 30, 181–199.CrossRefGoogle Scholar
  8. Derwent, R. G., Jenkin, M. E., Saunders, S. M., and Pilling, M. J., 1998: Photochemical ozone creation potentials for organic compounds in northwest Europe calculated with a master chemical mechanism, Atm. Environ. 32, 2429–2441.CrossRefGoogle Scholar
  9. Hein, R., Crutzen, P. J., and Heiman, M., 1997: An inverse modelling approach to investigate the global atmospheric methane cycle, Glob. Biogeochem. Cyc. 11, 43–76. http://www.epa.gov/oppt/exposure/docs/episuitedl.htm. CrossRefGoogle Scholar
  10. Kramp, F. and Paulson, S. E., 1998: On the uncertainties in the rate coefficients for the OH reactions with hydrocarbons, and the rate coefficients of the 1,3,5-Trimethylbenzene and m-xylene reactions with OH radicals in the gas phase, J. Phys. Chem. A. 102, 2685–2690.CrossRefGoogle Scholar
  11. Logan, J. A., 1985: Tropospheric ozone: Seasonal behavior, trends, and antropogenic influence, J. Geophys. Res. 90, 10463–10482.CrossRefGoogle Scholar
  12. Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Huie, R. E., Orkin, V. L., Moortgat, G. K., Ravishankara, A. R., Kolb, C. E., Molina, L. T., and Finlayson-Pitts, B. J., 2003: Chemical Kinetics and Photochemical data for use in atmospheric studies, JPL Publication 14.Google Scholar
  13. Scanlon, J. T. and Willis, D. E., 1985: Calculation of flame ionisation detector relative response factors using the effective carbon number concept, J. Chromatogr. Sci 23, 333–340.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • G. Solignac
    • 1
  • I. Magneron
    • 1
  • A. Mellouki
    • 1
    Email author
  • A. Muñoz
    • 2
  • M. Martin Reviejo
    • 2
  • K. Wirtz
    • 2
  1. 1.LCSR-CNRSOrléans CedexFrance
  2. 2.CEAMParque TecnológicoPaternaSpain

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