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Journal of Oceanography

, Volume 73, Issue 5, pp 669–685 | Cite as

Distribution and stoichiometry of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb in seawater around the Juan de Fuca Ridge

  • Linjie ZhengEmail author
  • Tomoharu Minami
  • Shotaro Takano
  • Hideki Minami
  • Yoshiki Sohrin
Original Article

Abstract

A central theme of the ongoing GEOTRACES program is to improve the understanding of processes occurring at ocean interfaces with continents, sediments, and ocean crust. In this context, we studied the distributions of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb around the Juan de Fuca Ridge (JdFR) in total dissolvable (td), dissolved (d), and labile particulate (lp) fractions, which represent a fraction in unfiltered samples, filtered samples through an AcroPak capsule filter, and the difference between td and d, respectively. Al and Fe were dominated by lp-species, while Ni, Zn, and Cd were dominated by d-species with undetectable amounts of lp-species. Major findings in this study are as follows: (1) The continental margin (CM) provided large sources of Al, Mn, Fe, and Co from the surface to ~2000 m in depth. The supply from CM caused high surface concentrations of dMn and dCo, a subsurface (100–300 m depth) maximum of dCo, and intermediate (500–2000 m depth) maxima of lpAl and lpFe. The supply of dFe from CM was ~10 times that from the high-temperature hydrothermal activity at station BD21, which is located at ~3 km from the Middle Valley venting site and ~ 200 km from Vancouver Island. (2) DPb was maximum at the top layer of North Pacific Intermediate Water, probably owing to isopycnal transport of anthropogenic Pb via advection of subducted surface waters. Although dCo and dPb had different sources in the upper water, they showed a strong linearity below 300 m (r 2 = 0.95, n = 38), indicating concurrent scavenging. (3) A high-temperature hydrothermal plume occurred at a depth of 2300 m at BD21, accounting for maxima of dAl, dMn, dFe, lpCu, and lpPb and a minimum of dCu. (4) Strong bottom maxima of lpAl, lpMn, lpFe, lpCo, and lpPb occurred above the abyssal plain at the western foot of the JdFR, indicating resuspension of sediments. However, bottom maxima of d-species were apparent only for dAl and dCu.

Keywords

GEOTRACES North Pacific Ocean The Juan de Fuca Ridge Trace metals Total dissolvable species Dissolved species Labile particulate species Continental margin Hydrothermal activities Resuspension 

Abbreviations

JdFR

Juan de Fuca Ridge

td

Total dissolvable

d

Dissolved

lp

Labile particulate

NPIW

North Pacific Intermediate Water

PDW

Pacific Deep Water

CM

Continental margin

Notes

Acknowledgements

We thank the crew, officers, captain, and scientists onboard R/V Hakuho Maru during the KH-12-4 cruise for their help with sampling and routine analysis. We also thank the three reviewers and editor Prof. Nishioka for their critical and insightful comments that helped to improve this manuscript. This work was financed through grants from the Steel Industry Foundation for the Advancement of Environmental Protection Technology and from Grant-in-Aid of Scientific Research, the Ministry of Education, Culture, Sports, Science, and Technology of Japan.

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Copyright information

© The Oceanographic Society of Japan and Springer Japan 2017

Authors and Affiliations

  1. 1.Institute for Chemical ResearchKyoto UniversityUjiJapan
  2. 2.School of Biological SciencesTokai UniversitySapporoJapan

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