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Journal of Chemical Crystallography

, Volume 45, Issue 1, pp 20–25 | Cite as

Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH

  • Karl D. zur Loye
  • Allison M. Latshaw
  • Mark D. Smith
  • W. Michael Chance
  • Hans-Conrad zur LoyeEmail author
Original Paper

Abstract

Single crystals of Na4(AsO4)OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na4(AsO4)OH crystallizes in the orthorhombic space group Pnma with a = 8.9467(11) Å, b = 7.3854(9) Å, and c = 8.2395(10) Å. The moisture sensitive material exhibits a three-dimensional crystal structure consisting of isolated AsO4 3− tetrahedra with the charge balance maintained by Na+ and OH. The asymmetric unit consists of one arsenic atom, three sodium atoms, four oxygen atoms, and one hydroxyl hydrogen atom. Arsenic, sodium, and oxygen atoms, as well as the hydroxyl hydrogen, are located on mirror planes; sodium is located on an inversion center.

Graphical Abstract

The synthesis and crystal structure are reported for Na4(AsO4)OH

Keywords

Crystal growth Crystal structure Hydroflux Na4(AsO4)OH 

Notes

Acknowledgements

This research was supported by the National Science Foundation through Grant DMR-1301757.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Karl D. zur Loye
    • 1
  • Allison M. Latshaw
    • 1
  • Mark D. Smith
    • 1
  • W. Michael Chance
    • 1
  • Hans-Conrad zur Loye
    • 1
    Email author
  1. 1.Department of Chemistry and BiochemistryUniversity of South CarolinaColumbiaUSA

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