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Journal of Chemical Crystallography

, Volume 44, Issue 11–12, pp 543–547 | Cite as

Columnar Formation in Sodium Triphenylacetate

  • M. S. C. Henriques
  • M. A. David
  • M. Ramos SilvaEmail author
  • P. Martín-Ramos
  • T. M. R. Maria
  • J. A. Paixão
Original Paper
  • 162 Downloads

Abstract

A new sodium salt, sodium triphenylacetate has been synthesized and characterized by single-crystal X-ray diffraction: triclinic, P-1 with a = 8.3846(2) Å, b = 13.5992(3) Å, c = 15.5288(3) Å, α = 76.7270(11)°, β = 74.4500(11)°, γ = 84.7410(13)°, M W  = 656.65, V = 1659.42(6) Å3, Z = 2. The triphenylacetic molecules bridge the metallic ions forming an infinite columnar structure. Calorimetric data does not support the existence of a mesophase induced by temperature.

Graphical Abstract

A new sodium salt, aqua-μ2-aqua-μ2-triphenylacetato-μ4-triphenylacetato-disodium, has been synthesized and characterized by X-ray diffraction, differential scanning calorimetry and thermomicroscopy.

Keywords

Columnar structure Hydrogen bonds Flexible molecule Triphenylacetic acid Sodium salt 

Notes

Acknowledgments

This work was supported by funds from FEDER (Programa Operacional Factores de Competitividade COMPETE) and from FCT-Fundação para a Ciência e a Tecnologia under the Project PEst-C/FIS/UI0036/2014. Access to TAIL-UC facility funded under QREN-Mais Centro Project ICT/2009/02/012/1890 is gratefully acknowledged. P. Martín-Ramos would like to thank Iberdrola Foundation for its financial support.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • M. S. C. Henriques
    • 1
  • M. A. David
    • 1
    • 2
  • M. Ramos Silva
    • 1
    Email author
  • P. Martín-Ramos
    • 1
  • T. M. R. Maria
    • 3
  • J. A. Paixão
    • 1
  1. 1.CEMDRX, Physics DepartmentUniversidade de CoimbraCoimbraPortugal
  2. 2.Department of Applied PhysicsChalmers University of TechnologyGothenburgSweden
  3. 3.CQC, Chemistry Department, Faculdade de Ciências e TecnologiaUniversidade de CoimbraCoimbraPortugal

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