Journal of Chemical Crystallography

, Volume 43, Issue 9, pp 463–470 | Cite as

Two Distinct Cu(I) Coordination Polymers Based on Isoniazid and Different Bridged Groups

  • Zhengjing JiangEmail author
  • Pusu Zhao
  • Rongqing Li
  • Litao An
  • Zaichao Zhang
  • Jian Xu
Original Paper


Two coordination polymers of [CuSCN(INH)] n (1) and [CuCl(INH)] n (2) have been synthesized (where INH = isoniazid). Their crystal structures have been determined by X-ray single crystal diffraction and both of them belong to monoclinic system. The Cu(I) ions in 1 and 2 all adopt distorted tetrahedral geometries. The complex 1 belongs to Cc space group and the cell parameters are: a = 44.370(2) Å, b = 3.811(3) Å, c = 30.2800(19) Å, β = 132.87(3)° and Z = 4. The Cu(I) ion in 1 is coordinated to three SCN groups and one INH ligand and such coordination model result in a 2D networks construction. Complex 2 crystallizes in the P21/c space group and the cell parameters are: a = 7.0319(13) Å, b = 18.367(3) Å, c = 6.0644(11) Å, β = 93.466(2)° and Z = 4. Each copper atom in 2 is ligated by two INH ligands and two chlorine groups. Two copper atoms are asymmetrically bridged by two chlorine ligands to form a Cu2Cl2 unit. Each Cu2Cl2 fragment is bridged by four INH groups to form a 2D layer structure.

Graphical Abstract

Two 2D Cu (I) coordination polymers based on isoniazid and different bridged groups, [CuSCN(INH))] n and [CuCl(INH)] n were synthesized and characterized.


Isoniazid Copper(I) Coordination polymer Crystal structure Thermal analysis 



This work was supported by Fund of Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials (JSKC12113).


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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Zhengjing Jiang
    • 1
    • 2
    Email author
  • Pusu Zhao
    • 1
    • 2
  • Rongqing Li
    • 1
    • 2
  • Litao An
    • 1
    • 2
  • Zaichao Zhang
    • 1
    • 2
  • Jian Xu
    • 1
    • 2
  1. 1.Jiangsu Key Laboratory for the Chemistry of Low-Dimensional MaterialsHuaiyin Normal UniversityHuai’anPeople’s Republic of China
  2. 2.Jiangsu Key Laboratory for Biomassbased Energy and Enzyme TechnologyHuaiyin Normal UniversityHuai’anPeople’s Republic of China

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