Journal of Chemical Crystallography

, Volume 42, Issue 8, pp 803–808

Synthesis and Crystal Structures of Zn(II)/Co(II) Complexes with Condensed Heterocyclic Based 1,2,4-Triazole

  • Peng-Yuan Ma
  • Jian-Bin Zhang
  • Mei Bai
  • Duo-Zhi Wang
Original Paper

Abstract

Three Zn(II)/Co(II) coordination compounds with condensed heterocyclic based 1,2,4-triazole 8H-4,7-diphenyl-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazines (L1), and 8H-4-phenyl-7-(pyridine-2-yl)-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazines (L2), Co(L1)2Cl2 (1), Zn(L1)2Cl2 (2). and Co(L2)2Cl2 (3) were synthesized and structurally characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. Complexes 1, 2 and 3 have mononuclear structure, the mononuclear structures of 1 and 2 were further assembled by the C–H⋯Cl and C–H⋯N weak interactions into an infinite 2-D supramolecular sheet.

Graphical Abstract

L1 and L2 was prepared by the reaction of 3-phenyl-4-amino-5-sulfhydryl-1,2,4-triazole with 2-bromo-phenylethanone and 2-bromo-1-(2-pyridyl)ethanone, respectively. Three Zn(II)/Co(II) coordination compounds Co(L1)2Cl2 (1), Zn(L1)2Cl2 (2). and Co(L2)2Cl2 (3) were synthesized and structurally characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. Complexes 1, 2 and 3 have mononuclear structure. The mononuclear structures of 1 and 2 were further assembled by the C–H⋯Cl and C–H⋯N weak interactions into an infinite 2-D supramolecular sheet.

Keywords

Zn(II)/Co(II) complex Synthesis Crystal structure 

References

  1. 1.
    Perry JJ, Perman JA, Zaworotko MJ (2009) Chem Soc Rev 38:1400–1417CrossRefGoogle Scholar
  2. 2.
    Zhang W, Ye HY, Xiong RG (2009) Coord Chem Rev 253:2980–2997CrossRefGoogle Scholar
  3. 3.
    Luo TT, Tsai HL, Yang SL, Liu YH, Yadav RD, Su CC, Ueng CH, Lin LG, Lu KL (2005) Angew Chem Int Ed Engl 44:6063–6067CrossRefGoogle Scholar
  4. 4.
    Cotton FA, Lin C, Murillo CA (2001) Acc Chem Res 34:759–771CrossRefGoogle Scholar
  5. 5.
    Chen B, Eddaoudi M, Reineke TM, Kampf JW, Opkeeffe M, Yaghi OM (2000) J Am Chem Soc 122:11559–11560CrossRefGoogle Scholar
  6. 6.
    Wang DZ, Liu CS, Li JR, Li L, Zeng YF, Bu XH (2007) CrystEngComm 9:289–297CrossRefGoogle Scholar
  7. 7.
    Su CY, Cai YP, Chen CL, Lissner F, Kang BS, Kaim W (2002) Angew Chem Int Ed Engl 41:3371–3375CrossRefGoogle Scholar
  8. 8.
    Wang DZ (2009) J Mol Struct 929:128–133CrossRefGoogle Scholar
  9. 9.
    Sun CY, Zheng XJ, Gao S, Li LC, Jin LP (2005) Eur J Inorg Chem 20:4150–4159CrossRefGoogle Scholar
  10. 10.
    Peng MX, Li CJ, Tong ML (2008) Inorg Chem Commun 11:707–710CrossRefGoogle Scholar
  11. 11.
    Xie XF, Chen SP, Xia ZQ, Gao SL (2009) Polyhedron 28:679–688CrossRefGoogle Scholar
  12. 12.
    Ghassemzadeh H, Bahemmat S, Mahmoodabadi M, Rezaii-Rad B, Monfared HH, Mottefakeri E, Neumüller B (2010) Polyheron 29:3036–3045CrossRefGoogle Scholar
  13. 13.
    Zhou JH, Cheng RM, Song Y, Li YZ, Yu Z, Chen XT, You XZ (2006) Polyheron 25:2426–2432CrossRefGoogle Scholar
  14. 14.
    Liu XG, Wang LY, Zhu X, Li BL, Zhang Y (2009) Cryst Growth Des 9:3997–4005CrossRefGoogle Scholar
  15. 15.
    Liu YY, Huang YQ, Shi W, Cheng P, Liao DZ, Yan SP (2007) Cryst Growth Des 7:1483–1489CrossRefGoogle Scholar
  16. 16.
    Obushak ND, Pokhodylo NT, Krupa II, Matiichuk VS (2007) Russ J Org Chem 43(8):1223–1227CrossRefGoogle Scholar
  17. 17.
    Bruker AXS (1998) SAINT software reference manual. MadisonGoogle Scholar
  18. 18.
    Sheldrick GM (1997) SHELXTL NT Version 5.1. Program for solution and refinemen of crystal structures. University of Göttingen, GermanyGoogle Scholar
  19. 19.
    Wang XW, Chen JZ, Liu JH (2007) Cryst Growth Des 7:1227–1229CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Peng-Yuan Ma
    • 1
  • Jian-Bin Zhang
    • 2
  • Mei Bai
    • 1
  • Duo-Zhi Wang
    • 1
  1. 1.Xinjiang Laboratory of Advanced Functional MaterialsChemistry and Chemical Engineering School of Xinjiang UniversityUrumqiPeople’s Republic of China
  2. 2.Physics and Chemistry Test Center of Xinjiang UniversityUrumqiPeople’s Republic of China

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