Journal of Chemical Crystallography

, Volume 41, Issue 9, pp 1406–1410 | Cite as

Syntheses, Structures, Fluorescence and Magnetic Property of Two Complexes with the Asymmetric dpa Ligand

  • Yan-Hua Liu
  • Ling-Fei Zeng
  • Pei-Qi Qiao
  • Yun-Tao Shi
  • Xin Liu
  • Wen Gu
Original Paper
First Online:
Received:
Accepted:
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Abstract

Two compounds [Zn(Hdpa)2(2,2′-bipy)]2 (1) and [Mn(dpa)(4,4′-bipy)] n (2) (H2dpa=2,2′-biphenyldicarboxylate, bipy=dipyridine) are synthesized by hydrothermal reactions and structurally characterized by Single crystal X-ray diffraction analyses. Compound 1 is a dual-core molecular structure of two Zn ions in the same coordination environment, we studied the fluorescence of compound 1. Compound 2 is a layer structure based on the one-dimensional chains bridged by 4,4-bipy, it displays weak antiferromagnetic interactions between the inter-chain Mn2+ ions.

Graphical Abstract

Two compounds were synthesized by hydrothermal reactions and structurally characterized by Single crystal X-ray diffraction analyses, and we studied the fluorescence and magnetic property.

Keywords

Fluorescence Magnetic dpa Dipyridine 
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Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21071083 and No. 20771062) and Tianjin Science Foundation (No. 08JCZDJC21100), and was also supported by “100 projects” of Creative Research for the Undergraduates of Nankai University.

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Yan-Hua Liu
    • 1
  • Ling-Fei Zeng
    • 2
  • Pei-Qi Qiao
    • 2
  • Yun-Tao Shi
    • 2
  • Xin Liu
    • 2
  • Wen Gu
    • 2
  1. 1.Department of ChemistryChiFeng UniversityChiFengChina
  2. 2.Department of ChemistryNankai UniversityTianjinChina

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